Skip to main content
SpringerLink
Log in

Structural Relaxation

  • Chapter
  • First Online:
Classical Relaxation Phenomenology

Abstract

Relaxation of dynamic and thermodynamic properties in amorphous materials is discussed for temperatures above, within, and below the glass transition temperature range.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Change history

  • 23 April 2020

    The original version of this book were inadvertently published with multiple typographical errors and the same has been updated.

References

  1. Angell, C.A., Ngai, K.L., McKenna, G.B., McMillan, P.F., Martin, S.W.: J. Appl. Phys. 88, 3113 (2000)

    CAS  Google Scholar 

  2. Klein, I.S., Angell, C.A.: J. Non-Cryst. Solids. 451, 116 (2016)

    CAS  Google Scholar 

  3. Scherer, G.W.: J. Amer. Ceram. Soc. 75, 1063 (1992)

    Google Scholar 

  4. Hodge, I.M.: J. Non-Cryst. Solids. 202, 164 (1996)

    CAS  Google Scholar 

  5. Adam, G., Gibbs, J.H.: J. Chem. Phys. 43, 139 (1965)

    CAS  Google Scholar 

  6. Angell, C.A.: Polymer. 38, 6261 (1997)

    CAS  Google Scholar 

  7. Macedo, P.B., Napolitano, A.: J. Chem. Phys. 49, 1887 (1968)

    CAS  Google Scholar 

  8. Goldstein, M.: J. Chem. Phys. 43, 1852 (1965)

    CAS  Google Scholar 

  9. Plazek, D.J., Magill, J.H.: J. Chem. Phys. 45, 3038 (1966)

    CAS  Google Scholar 

  10. Magill, J.H.: J. Chem. Phys. 47, 2802 (1967)

    CAS  Google Scholar 

  11. Howell, F.S., Bose, P.A., Macedo, P.B., Moyhihan, C.T.: J. Phys. Chem. 78, 639 (1974)

    CAS  Google Scholar 

  12. Scherer, G.W.: J. Am. Ceram. Soc. 67, 504 (1984)

    CAS  Google Scholar 

  13. Hodge, I.M.: Macromolecules. 20, 2897 (1987)

    CAS  Google Scholar 

  14. Richert, R., Angell, A.A.: J. Chem. Phys. 108, 9016 (1998)

    CAS  Google Scholar 

  15. Rendell, R.W., Fong, C.R., Ngai, K.L., Aklonis, J.J.: Macromolecules. 20, 1070 (1987)

    CAS  Google Scholar 

  16. Goldstein, M.: Ann. N. Y. Acad. Sci. 279, 68 (1976)

    CAS  Google Scholar 

  17. Goldstein, M.: J. Chem. Phys. 64, 4767 (1976)

    CAS  Google Scholar 

  18. Ngai, K.L.: Relaxation and Diffusion in Complex Systems. Springer, New York (2011). ISBN 978-1-4419-7648-2

    Google Scholar 

  19. Mathot, V.B.F.: Polymer. 25, 579 (1984)

    CAS  Google Scholar 

  20. Hodge, I.M.: J. Res. Natl. Inst. Stand. Technol. 102, 195 (1997)

    CAS  Google Scholar 

  21. Hodge, I.M.: Mater. Res. Soc. Symp. Proc. 215, 11 (1991)

    CAS  Google Scholar 

  22. Hodge, I. M.: Science. 267, 1945 (1995)

    Google Scholar 

  23. Struik, L.C.E.: Physical Aging in Amorphous Polymers and Other Materials. Elsevier, Amsterdam (1978)

    Google Scholar 

  24. Hodge, I.M.: J. Non-Cryst. Solids. 169, 211 (1994)

    CAS  Google Scholar 

  25. Hopkins, I.L.: J. Polym. Sci. 28, 631 (1958)

    CAS  Google Scholar 

  26. Gardon, R., Narayanaswamy, O.S.: J. Am. Ceram. Soc. 53, 380 (1970)

    CAS  Google Scholar 

  27. Tool, A.Q., Eichlin, C.G., presentation at American Ceramic Society meeting, Atlantic City (1924)

    Google Scholar 

  28. Tool, A.Q., Eichlin, C.G.: J. Am. Ceram. Soc. 14, 276 (1931)

    CAS  Google Scholar 

  29. Tool, A.Q.: J. Am. Ceram. Soc. 29, 240 (1946)

    CAS  Google Scholar 

  30. Moynihan, C.T., personal communication

    Google Scholar 

  31. Grassia, L., Koh, Y.P., Ropsa, M., Simon, S.L.: Macromolecules. 51, 1549 (2018)

    CAS  Google Scholar 

  32. Hodge, I.M., Berens, A.R.: Macromolecules. 18, 1980 (1985)

    CAS  Google Scholar 

  33. Berens, A.R., Hodge, I.M.: Polym. Eng. Sci. 24, 1123 (1984)

    CAS  Google Scholar 

  34. Ferry, J.D.: Viscoelastic Properties of Polymers. Wiley, New York (1980)

    Google Scholar 

  35. Johari, G.P., Goldstein, M.: J. Chem. Phys. 53(6), 2372 (1970)

    CAS  Google Scholar 

  36. Donth, E.: Relaxation and Thermodynamics in Polymers—Glass Transition. Akademie Verlag, Berlin (1992). ISBN 3-05-501392-1

    Google Scholar 

  37. Donth, E.: The Glass Transition. Springer, Berlin (2001). ISBN 3-540-41801-6

    Google Scholar 

  38. Angell, C.A.: Science. 267, 1924 (1995)

    CAS  Google Scholar 

  39. Scherer, G.W.: Relaxation in Glasses and Composites. Wiley, New York (1986)

    Google Scholar 

  40. Anderson, P.W.: Science. 267, 1615 (1995)

    CAS  Google Scholar 

  41. Moynihan, C.T.: In: Seyler, R.J. (ed.) Assignment of the Glass Transition, ASTM STP 1249, pp. 32–49 (1994)

    Google Scholar 

  42. Hodge, I.M.: unpublished internal Kodak Research Report (1989)

    Google Scholar 

  43. Phillies, G.D.J., Uhlmann, G.S., Uhlmann, K.: J. Chem. Phys. 82, 5242 (1985)

    CAS  Google Scholar 

  44. Kauzmann, W.: Chem. Rev. 43, 219 (1948)

    CAS  Google Scholar 

  45. Angell, C.A.: In: Ngai, K.L., Wright, G.B. (eds.) Relaxations in Complex Systems. Office Naval Research, Arlington, VA (1984)

    Google Scholar 

  46. Richet, P., Bottinga, J.: Geochim. Cosmochim. Acta. 48, 453 (1984)

    CAS  Google Scholar 

  47. Angell, C.A., Smith, D.R.: J. Phys. Chem. 86, 3845 (1982)

    CAS  Google Scholar 

  48. Martinez, L.-M., Angell, C.A.: Nature. 410, 663 (2001)

    CAS  Google Scholar 

  49. Stillinger, F.: J. Chem. Phys. 88, 7818 (1988)

    CAS  Google Scholar 

  50. Angell, C.A., MacFarlane, D.R., Oguni, M.: Ann. N. Y. Acad. Sci. 484, 241 (1984)

    Google Scholar 

  51. Vuillard, G.: Ann. Chim. 2, 223 (1957)

    Google Scholar 

  52. Sare, E.J.: PhD Thesis, Purdue University (1970)

    Google Scholar 

  53. Gibbs, J.H., DiMarzio, E.A.: J. Chem. Phys. 28, 373 (1958)

    CAS  Google Scholar 

  54. Gujrati, P.D., Goldstein, M.: J. Chem. Phys. 74, 2596 (1981)

    Google Scholar 

  55. DiMarzio, E.A., Guttman, C.M.: Macromolecules. 20, 1403 (1987)

    CAS  Google Scholar 

  56. Yang, A.J.-M., DiMarzio, E.A.: Macromolecules. 24, 6102 (1991)

    Google Scholar 

  57. Matyushov, D.V., Angell, C.A.: J. Chem. Phys. 123, 034506 (2005)

    Google Scholar 

  58. Angell, C.A., Rao, K.J.: J. Chem. Phys. 57, 470 (1972)

    CAS  Google Scholar 

  59. Hodge, I.M., unpublished results

    Google Scholar 

  60. Angell, C.A.: In: Wolynes, P.G., Lubchenko, V. (eds.) Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications, pp. 237–278. Wiley, Hoboken (2012)

    Google Scholar 

  61. Fermi, E.: Thermodynamics, p. 142. Dover, New York (1956)

    Google Scholar 

  62. Easteal, A.J., Angell, C.A.: J. Phys. Chem. 74, 3987 (1970) and references therein

    Google Scholar 

  63. Angell, C.A., Sare, E.J.: J. Phys. Chem. 52, 1058 (1970)

    CAS  Google Scholar 

  64. Moynihan, C.T., Easteal, A.J., DeBolt, M.A., Tucker, J.: J. Am. Ceram. Soc. 59, 12 (1976)

    CAS  Google Scholar 

  65. Hodge, I.M.: J. Pharm. Sci. 102, 2236 (2013)

    Google Scholar 

  66. Schick, C.: Handbook of Thermal Analysis and Calorimetry, vol. 3. Elsevier, Amsterdam (2002)

    Google Scholar 

  67. Hodge, I.M., Heslin, R.: J. Non-Cryst. Solids. 356, 1479 (2010)

    CAS  Google Scholar 

  68. Pappin, A.J., Hutchinson, J.M., Ingram, M.D.: Macromolecules. 25, 1084 (1992)

    CAS  Google Scholar 

  69. Hodge, I.M., Berens, A.R.: Macromolecules. 15, 762 (1982)

    CAS  Google Scholar 

  70. Hodge, I.M.: Macromolecules. 16, 898 (1983)

    CAS  Google Scholar 

  71. Gray, A.P.: In: Porter, R., Johnson, J.F. (eds.) Analytical Calorimetry. Plenum, New York (1968)

    Google Scholar 

  72. Lagasse, R.R.: J. Polym. Sci. Polym. Phys. Ed. 20, 279 (1982)

    CAS  Google Scholar 

  73. Mraw, S.C.: Rev. Sci. Instrum. 53, 228 (1982)

    CAS  Google Scholar 

  74. Richardson, M.J., Burrington, P.: J. Therm. Anal. 6, 345 (1974)

    CAS  Google Scholar 

  75. Hutchinson, J.M.: Progr. Colloid Polym. Sci. 87, 69 (1992)

    CAS  Google Scholar 

  76. Hutchinson, J.M., Ruddy, M., Wilson, M.R.: Polymer. 29, 152 (1988)

    CAS  Google Scholar 

  77. Hutchinson, J.M., Ruddy, M.: J. Polym. Sci. 26, 2341 (1988)

    CAS  Google Scholar 

  78. Lesikar, A.V., Moynihan, C.T.: J. Chem. Phys. 73, 1932 (1980)

    CAS  Google Scholar 

  79. Lesikar, A.V., Moynihan, C.T.: J. Chem. Phys. 72, 6422 (1980)

    CAS  Google Scholar 

  80. Hodge, I.M., unpublished calculations

    Google Scholar 

  81. Sartor, G., Mayer, E., Johari, G.P.: Biophys. J. 66, 249 (1994)

    CAS  Google Scholar 

  82. Tombari, E., Johari, G.P.: J. Chem. Phys. 139, 105102 (2013)

    Google Scholar 

  83. Wunderlich, B., Jones, L.D.: J. Macromol. Sci., Part B. 3, 67 (1969)

    CAS  Google Scholar 

  84. Sales, B.C.: J. Non-Cryst. Solids. 119, 136 (1990)

    CAS  Google Scholar 

  85. Hodge, I.M., O’Reilly, J.M.: J. Phys. Chem. B. 103, 4171 (1999)

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Physics and Astronomy (retired), Rochester Institute of Technology, Rochester, NY, USA

    Ian M. Hodge

Authors
  1. Ian M. Hodge
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Hodge, I.M. (2019). Structural Relaxation. In: Classical Relaxation Phenomenology. Springer, Cham. https://doi.org/10.1007/978-3-030-02459-8_11

Download citation

Publish with us

Policies and ethics

Search

Navigation