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Theoretical Thermogravimetric Analysis at Constant Heating Rates

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Thermal Analysis

Abstract

Let the general reaction rate equation be a function h (α,T) of the conversion a and the temperature T. Then the evolution, with the heating rate ø, of a, T and the experimental rate υ can be forecasted at the maximum of the rate under peculiar conditions. For instance, if h (α,T) = k(T)(1-α)n, it can be shown that an increase of υm compels related increase of Tm and decrase of υm. Regarding am, it increases first with ø up to a value αmo and decreases thereafter.

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© 1980 Springer Basel AG

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Comel, C., Veron, J., Bouster, C., Vermande, P. (1980). Theoretical Thermogravimetric Analysis at Constant Heating Rates. In: Wiedemann, H.G. (eds) Thermal Analysis. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-6719-1_6

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  • DOI: https://doi.org/10.1007/978-3-0348-6719-1_6

  • Publisher Name: Birkhäuser, Basel

  • Print ISBN: 978-3-0348-6720-7

  • Online ISBN: 978-3-0348-6719-1

  • eBook Packages: Springer Book Archive

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