Abstract
Lithium-sulfur (Li-S) batteries have been considered as one promising energy storage system for the electrification of vehicles, since their specific energy density is five times higher than that of lithium-ion batteries (2600 vs. 500 Wh kg−1). However, the insulating properties of the sulfur cathode, safety concerns of the lithium anode, and polysulfide shuttle effects in liquid electrolytes have hindered them from practical applications. In this book chapter, we first introduce brief fundamentals and key limitations associated with traditional Li-S batteries. We then focus discussion on recent advances in different components of Li-S liquid cells, including the sulfur cathode, the lithium anode, and the liquid electrolyte. We also discuss the important shift from traditional liquid cells to recent all-solid cells, with developments in both solid electrolyte and electrode material. Last but not least, we present future opportunities and perspectives for Li-S batteries.
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References
Winter M, Brodd RJ (2004) Chem Rev 104:4245
Bruce PG, Hardwick LJ, Abraham KM (2011) MRS Bull 36:506
Cavaliere S, Subianto S, Savych I, Jones DJ, Roziere J (2011) Energy Environ Sci 4:4761
Liu C, Li F, Ma LP, Cheng HM (2010) Adv Mater 22:E28
Cairns EJ, Albertus P (2010) Annu Rev Chem Biomol 1:299
Zhang WJ (2011) J Power Sources 196:13
Yang Y, Zheng GY, Cui Y (2013) Chem Soc Rev 42:3018
He XM, Pu WH, Ren JG, Wang L, Wang JL, Jiang CY, Wan CR (2007) Electrochim Acta 52:7372
Li Q, Zhang ZA, Zhang K, Fang J, Lai YQ, Li J (2014) J Power Sources 256:137
Peled E, Gorenshtein A, Segal M, Sternberg Y (1989) J Power Sources 26:269
Manthiram A, Fu YZ, Su YS (2013) Acc Chem Res 46:1125
Cheon SE, Ko KS, Cho JH, Kim SW, Chin EY, Kim HT (2003) J Electrochem Soc 150:A796
Cheon SE, Ko KS, Cho JH, Kim SW, Chin EY, Kim HT (2003) J Electrochem Soc 150:A800
Mikhaylik YV, Akridge JR (2004) J Electrochem Soc 151:A1969
Su YS, Fu YZ, Cochell T, Manthiram A (2013) Nat Commun 4:1331
Zhang SS (2013) J Power Sources 231:153
Yin YX, Xin S, Guo YG, Wan LJ (2013) Angew Chem Int Ed 52:13186
Scheers J, Fantini S, Johansson P (2014) J Power Sources 255:204
Evers S, Nazar LF (2013) Acc Chem Res 46:1135
Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM (2012) Nat Mater 11
Ellis BL, Lee KT, Nazar LF (2010) Chem Mater 22:691
Marom R, Amalraj SF, Leifer N, Jacob D, Aurbach D (2011) J Mater Chem 21:9938
Dunn B, Kamath H, Tarascon JM (2011) Science 334:928
Wang J, Xin HLL, Wang DL (2014) Part Part Syst Char 31:515
Fedorkova A, Orinakova R, Cech O, Sedlarikova M (2013) Int J Electrochem Sci 8:10308
Li WY, Zheng GY, Yang Y, Seh ZW, Liu N, Cui Y (2013) Proc Natl Acad Sci 110:7148
Wei SC, Zhang H, Huang YQ, Wang WK, Xia YZ, Yu ZB (2011) Energy Environ Sci 4:736
Shim J, Striebel KA, Cairns EJ (2002) J Electrochem Soc 149:A1321
Zhang SC, Zhang L, Wang WK, Xue WJ (2010) Synthetic Met 160:2041
Wang C, Chen JJ, Shi YN, Zheng MS, Dong QF (2010) Electrochim Acta 55:7010
Ji XL, Lee KT, Nazar LF (2009) Nat Mater 8:500
Xu GL, Xu YF, Fang JC, Peng XX, Fu F, Huang L, Li JT, Sun SG (2013) Acs Appl Mater Inter 5:10782
Yu LH, Brun N, Sakaushi K, Eckert J, Titirici MM (2013) Carbon 61:245
Xi K, Cao S, Peng XY, Ducati C, Kumar RV, Cheetham AK (2013) Chem Commun 49:2192
Wang XF, Fang XP, Guo XW, Wang ZX, Chen LQ (2013) Electrochim Acta 97:238
Tao XY, Chen XR, Xia Y, Huang H, Gan YP, Wu R, Chen F, Zhang WK (2013) J Mater Chem A 1:3295
Wang DW, Zeng QC, Zhou GM, Yin LC, Li F, Cheng HM, Gentle IR, Lu GQM (2013) J Mater Chem A 1:9382
Ye H, Yin YX, Xin S, Guo YG (2013) J Mater Chem A 1:6602
Zhao SR, Li CM, Wang WK, Zhang H, Gao MY, Xiong X, Wang AB, Yuan KG, Huang YQ, Wang F (2013) J Mater Chem A 1:3334
Hwang TH, Jung DS, Kim JS, Kim BG, Choi JW (2013) Nano Lett 13:4532
Lu ST, Cheng YW, Wu XH, Liu J (2013) Nano Lett 13:2485
Park MS, Yu JS, Kim KJ, Jeong G, Kim JH, Yim T, Jo YN, Hwang U, Kang S, Woo T, Kim H, Kim YJ (2013) Rsc Adv 3:11774
Yang X, Zhang L, Zhang F, Huang Y, Chen YS (2014) ACS Nano 8:5208
Ma XZ, Jin B, Xin PM, Wang HH (2014) Appl Surf Sci 307:346
He G, Mandlmeier B, Schuster J, Nazar LF, Bein T (2014) Chem Mater 26:3879
Ding B, Yuan CZ, Shen LF, Xu GY, Nie P, Zhang XG (2013) Chem Eur J 1013:19
Wang B, Wen YF, Ye DL, Yu H, Sun B, Wang GX, Hulicova-Jurcakova D, Wang LZ (2014) Chem Eur J 20:5224
Wang JL, Yin LC, Jia H, Yu HT, He YS, Yang J, Monroe CW (2014) ChemSusChem 7:563
Chung SH, Manthiram A (2014) Electrochem Commun 38:91
Zhou L, Lin XJ, Huang T, Yu AS (2014) Electrochim Acta 116:210
Huang JQ, Peng HJ, Liu XY, Nie JQ, Cheng XB, Zhang Q, Wei F (2014) J Mater Chem A 2:10869
Qu YH, Zhang ZA, Wang XW, Lai YQ, Liu YX, Li J (2013) J Mater Chem A 1:14306
Jin KK, Zhou XF, Zhang LZ, Xin X, Wan GH, Liu ZP (2013) J Phys Chem C 117:21112
Cheng XB, Huang JQ, Zhang Q, Peng HJ, Zhao MQ, Wei F (2014) Nano Energy 4:65
Brun N, Sakaushi K, Yu LH, Giebeler L, Eckert J, Titirici MM (2013) Phys Chem Chem Phys 15:6080
Lu ST, Chen Y, Wu XH, Wang ZD, Lv LY, Qin W, Jiang LX (2014) Rsc Adv 4:18052
Tang JJ, Yang J, Zhou XY (2013) Rsc Adv 3:16936
Xin S, Gu L, Zhao NH, Yin YX, Zhou LJ, Guo YG, Wan LJ (2012) J Am Chem Soc 134:18510
Qu Y, Zhang Z, Zhang X, Ren G, Lai Y, Liu Y, Li J (2015) J Mater Chem A 84:399
Strubel P, Thieme S, Biemelt T, Helmer A, Oschatz M, Brückner J, Althues H, Kaskel S (2015) Adv Funct Mater 25:287
Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Nature 438:197
Zhang YG, Zhao Y, Konarov A, Gosselink D, Soboleski HG, Chen P (2013) J Power Sources 241:517
Lu LQ, Lu LJ, Wang Y (2013) J Mater Chem A 1:9173
Lin TQ, Tang YF, Wang YM, Bi H, Liu ZQ, Huang FQ, Xie XM, Jiang MH (2013) Energ. Environ Sci 6:1283
Huang JQ, Liu XF, Zhang Q, Chen CM, Zhao MQ, Zhang SM, Zhu WC, Qian WZ, Wei F (2013) Nano Energy 2:314
Yan Y, Yin YX, Xin S, Guo YG, Wan LJ (2012) Chem Commun 48:10663
Li NW, Zheng MB, Lu HL, Hu ZB, Shen CF, Chang XF, Ji GB, Cao JM, Shi Y (2012) Chem Commun 48:4106
Ji LW, Rao MM, Zheng HM, Zhang L, Li YC, Duan WH, Guo JH, Cairns EJ, Zhang YG (2011) J Am Chem Soc 133:18522
Yu M, Wang A, Tian F, Song H, Wang Y, Li C, Hong J-D, Shi G (2015) Nanoscale 7:5292
Zhao Y, Wu W, Li J, Xu Z, Guan L (2014) Adv Mater 26:5113
Sun L, Kong W, Jiang Y, Wu H, Jiang K, Wang J, Fan S (2015) J Mater Chem A 3:5305
Yin LC, Wang JL, Yang J, Nuli YN (2011) J Mater Chem 21:6807
Xiao LF, Cao YL, Xiao J, Schwenzer B, Engelhard MH, Saraf LV, Nie ZM, Exarhos GJ, Liu J (2012) Adv Mater 24:1176
Wu F, Chen JZ, Chen RJ, Wu SX, Li L, Chen S, Zhao T (2011) J Phys Chem C 115:6057
Zhang Z, Li Q, Lai YQ, Li J (2014) J Phys Chem C 118:13369
Jin J, Wen ZY, Ma GQ, Lu Y, Rui K (2014) Solid State Ionics 262:170
Aleksandrov IA, Abramchuk SS, Solodovnikov SP, Zezin SB, Shevchenko VG, Aleksandrov AI (2012) Polym Sci Ser 54:407
Wang W, Li GC, Wang Q, Li GR, Ye SH, Gao XP (2013) J Electrochem Soc 160:A805
Zhang YG, Bakenov Z, Zhao Y, Konarov A, The NLD, Malik M, Paron T, Chen P (2012) J Power Sources 208:1
Zhou WD, Yu YC, Chen H, DiSalvo FJ, Abruna HD (2013) J Am Chem Soc 135:16736
Wang X, Zhang Z, Yan X, Qu Y, Lai Y, Li J (2015) Interface polymerization synthesis of conductive polymer/graphite oxide@sulfur composites for high-rate lithium-sulfur batteries. Electrochem Acta 155:54
Yang Y, Zheng GY, Misra S, Nelson J, Toney MF, Gui Y (2012) J Am Chem Soc 134:15387
Yang ZC, Guo JC, Das SK, Yu YC, Zhou ZH, Abruna HD, Archer LA (2013) J Mater Chem A 1:1433
Jeong S, Bresser D, Buchholz D, Winter M, Passerini S (2013) J Power Sources 235:220
Yang Y, McDowell MT, Jackson A, Cha JJ, Hong SS, Cui Y (2010) Nano Lett 10:1486
Hassoun J, Sun YK, Scrosati B (2011) J Power Sources 196:343
Fu YZ, Su YS, Manthiram A (2014) Adv Energy Mater 4:1300655
Lin Z, Nan C, Ye Y, Guo J, Zhu J, Cairns EJ (2014) Nano Energy 9:408
Nan C, Lin Z, Liao H, Song M-K, Li Y, Cairns EJ (2014) J Am Chem Soc 136:4659
Xiong SZ, Kai X, Hong XB, Diao Y (2012) Ionics 18:249
Aurbach D, Pollak E, Elazari R, Salitra G, Kelley CS, Affinito J (2009) J Electrochem Soc 156:A694
Lin Z, Liu ZC, Fu WJ, Dudney NJ, Liang CD (2013) Adv Funct Mater 1064:23
Zheng G, Lee SW, Liang Z, Lee H-W, Yan K, Yao H, Wang H, Li W, Chu S, Cui Y (2014) Nat Nanotech 9:618
Zhao Y, Wu WL, Li JX, Xu ZC, Guan LH (2014) Adv Mater 26:5113
Wu FX, Kim H, Magasinski A, Lee JT, Lin HT, Yushin G (2014) Adv Energy Mater 4. doi:10.1002/aenm.201400196
Sun L, Li MY, Jiang Y, Kong WB, Jiang KL, Wang JP, Fan SS (2014) Nano Lett 14:4044
Rong JP, Ge MY, Fang X, Zhou CW (2014) Nano Lett 14:473
Chang DR, Lee SH, Kim SW, Kim HT (2002) J Power Sources 112:452
Ryu HS, Ahn HJ, Kim KW, Ahn JH, Cho KK, Nam TH, Kim JU, Cho GB (2006) J Power Sources 163:201
Choi JW, Kim JK, Cheruvally G, Ahn JH, Ahn HJ, Kim KW (2007) Electrochim Acta 52:2075
Gao J, Lowe MA, Kiya Y, Abruna HD (2011) J Phys Chem C 115:25132
Wang JL, Yang J, Wan CR, Du K, Xie JY, Xu NX (2003) Adv Funct Mater 13:487
Wang JL, Yang J, Xie JY, Xu NX (2002) Adv Mater 14:963
Yuan LX, Feng JK, Ai XP, Cao YL, Chen SL, Yang HX (2006) Electrochem Commun 8:610
Rao MM, Song XY, Cairns EJ (2012) J Power Sources 205:474
Shin JH, Cairns EJ (2008) J Power Sources 177:537
Song M-K, Zhang Y, Cairns EJ (2013) Nano Lett 13:5891
Peled E, Sternberg Y, Gorenshtein A, Lavi Y (1989) J Electrochem Soc 136:1621
Yamin H, Gorenshtein A, Penciner J, Sternberg Y, Peled E (1988) J Electrochem Soc 1045:135
Park JW, Ueno K, Tachikawa N, Dokko K, Watanabe M (2013) J Phys Chem C 117:20531
Ueno K, Park JW, Yamazaki A, Mandai T, Tachikawa N, Dokko K, Watanabe M (2013) J Phys Chem C 117:20509
Weng W, Pol VG, Amine K (2013) Adv Mater 25:1608
Park MS, Jeong BO, Kim TJ, Kim S, Kim KJ, Yu JS, Jung Y, Kim YJ (2014) Carbon 68:265
Agrawal RC, Pandey GP (2008) J Phys D-Appl Phys 41
Quartarone E, Mustarelli P (2011) Chem Soc Rev 40:2525
Bouchet R, Maria S, Meziane R, Aboulaich A, Lienafa L, Bonnet JP, Phan TNT, Bertin D, Gigmes D, Devaux D, Denoyel R, Armand M (2013) Nat Mater 12:452
Jeddi K, Ghaznavi M, Chen P (2013) J Mater Chem A 1:2769
Marmorstein D, Yu TH, Striebel KA, McLarnon FR, Hou J, Cairns EJ (2000) J Power Sources 89:219
Nagao M, Imade Y, Narisawa H, Kobayashi T, Watanabe R, Yokoi T, Tatsumi T, Kanno R (2013) J Power Sources 222:237
Youngsik K, Arumugam N, Goodenough JB (2008) Chem Mater 20:470
Nagao M, Hayashi A, Tatsumisago M (2011) Electrochim Acta 56:6055
Liang XA, Wen ZY, Liu Y, Zhang H, Huang LZ, Jin J (2011) J Power Sources 196:3655
Kamaya N, Homma K, Yamakawa Y, Hirayama M, Kanno R, Yonemura M, Kamiyama T, Kato Y, Hama S, Kawamoto K, Mitsui A (2011) Nat Mater 10:682
Hakari T, Nagao M, Hayashi A, Tatsumisago M (2014) Solid State Ionics 262:147
Nagao M, Hayashi A, Tatsumisago M (2011) J Power Sources 196:6902
Hayashi A, Ohtsubo R, Nagao M, Tatsumisago M (2010) J Mater Sci 45:377
Ohtomo T, Hayashi A, Tatsumisago M, Kawamoto K (2013) J Non-Cryst Solids 364:57
Ito Y, Sakuda A, Ohtomo T, Hayashi A, Tatsumisago M (2013) Solid State Ionics 236:1
Muramatsu H, Hayashi A, Ohtomo T, Hama S, Tatsumisago M (2011) Solid State Ionics 182:116
Liu ZC, Fu WJ, Payzant EA, Yu X, Wu ZL, Dudney NJ, Kiggans J, Hong KL, Rondinone AJ, Liang CD (2013) J Am Chem Soc 135:975
Lin Z, Liu ZC, Dudney NJ, Liang CD (2013) ACS Nano 7:2829
Lin Z, Liu Z, Fu W, Dudney NJ, Liang C (2013) Angew Chem Int Ed 52:7460
Sahu G, Lin Z, Li JC, Liu ZC, Dudney N, Liang CD (2014) Energy Environ Sci 1053:7
Hayashi A, Ohtomo T, Mizuno F, Tadanaga K, Tatsumisago M (2003) Electrochem Commun 5:701
Takeuchi T, Kageyama H, Nakanishi K, Tabuchi M, Sakaebe H, Ohta T, Senoh H, Sakai T, Tatsumi K (2010) J Electrochem Soc 157:A1196
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Li, S., Lin, Z. (2015). Lithium-Sulfur Battery. In: Zhang, Z., Zhang, S. (eds) Rechargeable Batteries. Green Energy and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-15458-9_21
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