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Viscous Flow of Glass-Forming Liquids and Glasses

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Physics of Liquid Matter: Modern Problems

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 171))

Abstract

Continuous liquid-to-glass transition is characterized by dramatic changes of the liquid structure, thermodynamics and dynamics in a comparatively narrow temperature range. The viscous flow modes of the matter are changing within this temperature range too. The interplay of the structural, thermodynamic, mechanical and dynamic parameters at the viscous flow is still a challenge. Near the glass transition temperature the cooperative diffusion and sliding determine the shear viscosity of the liquid and glass as well as the fragility and the strain rate sensitivity of the flow. In this chapter the theoretical aspects of the physics of viscous flow of glass-forming liquids and glasses are considered within the framework of the heterophase fluctuations model (HPFM), providing a mesoscopic description of the heterophase liquid states. Newtonian and non-Newtonian, Arrhenius and non-Arrhenius flow modes are considered as well as the crossover from the flow to inhomogeneous deformation of glass. The fragility, the strain rate sensitivity, and the fragile-to-strong liquid transformation are described.

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Notes

  1. 1.

    Mesoscopically equilibrated glasses have non-zero residual configurational entropy at \(T \to 0\) [12].

  2. 2.

    In Argon’s model of homogeneous creep of metallic glasses the activation volume is taken \({ \approx }30a^{3}\) [28].

  3. 3.

    Cooperative structural fluctuations of such type were introduced by Argon [28]. Later they were termed “shear transformation zones” STZs [53].

  4. 4.

    Comprehensive overviews of the inhomogeneous deformation and shear banding of metallic glasses are presented in [6, 56]. The scenario with two consecutive stages of the shear band formation is considered in [56] and the references quoted.

Abbreviations

AG:

Adam-Gibbs

CD:

correlated domains

CRD:

cooperatively rearranging domain

DVF:

diffusion-viscous flow

HPF:

heterophase fluctuations

HPFM:

heterophase fluctuations model

SRO:

short-range order

SRS:

strain rate sensitivity

STZ:

shear transformation zone

VFT:

Vogel-Fulcher-Tamman

WAXS:

wide-angle X-ray scattering

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Acknowledgments

I express my thanks to Dr. N.P. Lazarev for valuable comments.

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Authors and Affiliations

  1. The National Scientific Center Kharkiv Institute of Physics and Technology (Formerly the Ukrainian Institute of Physics and Technology), 1, Akademichna Str, Kharkiv, 61108, Ukraine

    Olexandr Bakai

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Editors and Affiliations

  1. Faculty of Physics, Taras Shevchenko National University, Kyiv, Ukraine

    Leonid Bulavin

  2. Head of Department of Physical Chemistry of Disperse Minerals, Biocolloidal Chemistry Institute, Kiev, Ukraine

    Nikolai Lebovka

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Bakai, O. (2015). Viscous Flow of Glass-Forming Liquids and Glasses. In: Bulavin, L., Lebovka, N. (eds) Physics of Liquid Matter: Modern Problems. Springer Proceedings in Physics, vol 171. Springer, Cham. https://doi.org/10.1007/978-3-319-20875-6_5

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