Skip to main content

Removal of Phenylacetic Acid from Aqueous Streams

  • Conference paper
  • First Online:
Biofuels and Bioenergy (BICE2016)

Part of the book series: Springer Proceedings in Energy ((SPE))

  • 710 Accesses

Abstract

Phenylacetic acid is a carboxylic acid found in the active auxin. Phenylacetic acid is extensively used in the biotechnological and pharmaceutical industry for the production of β-lactam, antibiotics, penicillin G etc. Phenylacetic acid has wide range of biological activity, antibacterial, analgesic, and virucidal properties. Because of versatile biological and medicinal activities of the phenylacetic acid, it is necessary to recover it from the aqueous streams. Separation of phenylacetic acid from aqueous streams is an essential fraction of their manufacturing process which directly affects the economy of the process. Number of separation methods such as ion-exchange, adsorption, reverse osmosis, electro-dialysis, distillation, precipitation, ultrafiltration, extraction etc. Most of these methods have their certain drawback. Among all these methods, adsorption method is preferable including biological, physical, and chemical, natural systems due its low cost, high treatment stability, easy operation and compact facility. Further the exhaustive comparisons of these methods have been discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Wightman F, Lighty DL (1982) Identification of phenylacetic acid as a natural auxin in the shoots of higher plants. Physiol Plant 55:17–24

    Article  Google Scholar 

  2. Shrivastava R, Purohit H, Phale PS (2011) Metabolism and preferential utilization of phenylacetic acid and 4-hydroxyphenylacetic acid in pseudomonas putida CSV86. J Bioremediat Biodegradation 2:120. doi:10.4172/2155-6199.1000120

    Article  Google Scholar 

  3. Gunjan J, Awadh D (2011) Synthesis and biological evaluation of some phenyl acetic acid hydrazone derivatives. Int Res J Pharm 2:110–112

    Google Scholar 

  4. Ramchandran K, Krishnamurthy SA, Subbaraman SH (1996) Kinetics and reaction engineering of Pen-G hydrolysis. J Chem Technol Biotechnol 66:243–250

    Article  Google Scholar 

  5. Hammad Y, Nalin R, Marechal J, Fiasson K, Pepin R, Berry AM, Normand P, Domenach AM (2003) A possible role for phenyl acetic acid (phenylacetic acid) on alnus glutinosa nodulation by frankia. Plant Soil 254:193–205

    Article  Google Scholar 

  6. Xie YK, Pei LZ, Pei YQ, Cai ZY (2014) Determination of phenyl acetic acid by cyclic voltammetry with electrochemical detection. Measurement 47:341–344

    Article  Google Scholar 

  7. Mohamed ME, Ismail W, Heider J, Fuchs G (2002) Aerobic metabolism of phenylacetic acids in azoarcus evansii. Arch microbial 178:180–192

    Article  Google Scholar 

  8. Kaczmarek FS, Coykendall AL (1980) Production of phenylacetic acid by strains of bacteroides asaccharolyticus and bacteroides gingivalis (sp. nov.). J Clin Microbiol 12:288–290

    Google Scholar 

  9. Kim SH, Yang JL, Song YS (1999) Physiological functions of chungkuk-jang. Food Nutr Res 4:40–46

    Google Scholar 

  10. Yong HK, Choi HS, Hur SH, Hong JH (2001) Antimicrobial activities of viscous substances from chungkukjang fermented with different bacillus Spp. J Food Hyg Saf 16:288–293

    Google Scholar 

  11. Athankar KK, Wasewar KL, Varma MN, Shende DZ, Uslu H (2015) Extractive separation of benzylformic acid with phosphoric acid tributyl ester in CCl4, decanol, kerosene, toluene, and xylene at 298 K. J Chem Eng Data 60:1014–1022

    Article  Google Scholar 

  12. Gaidhani HK, Wasewar KL, Pangarkar VG (2002) Intensification of enzymatic hydrolysis of penicillin G: Part 1. Equilibria and kinetics of extraction of phenylacetic acid by alamine 336. Chem Eng Sci 57:1979–1984

    Article  Google Scholar 

  13. Adams R, Thal AF (1932) Phenylacetic acid. Org Synth 54:655

    Google Scholar 

  14. Uslu H (2006) Linear solvation energy relationship (LSER) modeling and kinetic studies on propionic acid reactive extraction using alamine 336 in a toluene solution. Ind Eng Chem Res 45:5788–5795

    Article  Google Scholar 

  15. Wasewar KL, Yoo CK (2012) Intensifying the recovery of carboxylic acids by reactive extraction. In: International conference on chemistry and chemical engineering. IACSIT Press, Singapore, p 38

    Google Scholar 

  16. Tuyun AF, Uslu H (2010) Extraction equilibria of picolinic acid from aqueous solution by tridodecylamine (TDA). Desalination 268:134–140

    Article  Google Scholar 

  17. Asci YS, Hasdemir IM (2008) Removal of some carboxylic acids from aqueous solutions by hydrogels. J Chem Eng Data 53:2351–2355

    Article  Google Scholar 

  18. Keshav A, Wasewar KL, Chand S (2008) Extraction of propionic acid with tri-n-octyl amine in different diluents. Sep Purif Technol 63:179–183

    Article  Google Scholar 

  19. Hong YK, Hong WH, Han DH (2001) Application of reactive extraction to recovery of carboxylic acids. Biotechnol Bioprocess Eng 6:386–394

    Article  Google Scholar 

  20. Athankar KK, Wasewar KL, Varma MN, Shende DZ (2015) Relative basicity approach for separation of α-toluic acid with triglycerides of fatty acids by reactive extraction. J Ind Eng Chem 22:240–247

    Article  Google Scholar 

  21. Athankar KK, Varma MN, Shende DZ, Yoo CK, Wasewar KL (2013) Reactive extraction of phenylacetic acid with tri-n-butyl phosphate in benzene, hexanol, and rice bran oil at 298 K. J Chem Eng Data 58:3240–3248

    Article  Google Scholar 

  22. Athankar KK, Wasewar KL, Varma MN, Shende DZ, Uslu H (2015) Extractive separation of benzylformic acid with phosphoric acid tributyl ester in CCl4, decanol, kerosene, toluene, and xylene at 298 K. J Chem Eng Data 60:1014–1022

    Article  Google Scholar 

  23. Ng TK, Busche RM, McDonald CC, Hardy RWF (1983) Production of feedstock chemicals. Science 219:733–740

    Article  Google Scholar 

  24. Tung LA, King CJ (1994) Sorption and extraction of lactic and succinic acids at pH > pKa1. I. factors governing equilibria. Ind Eng Chem Res 33:3217–3223

    Article  Google Scholar 

  25. Kawabata N, Yasuda S, Yamazaki T (1982) Process for recovering a carboxylic acid, US Patent, 4323702

    Google Scholar 

  26. Inci I (2005) Adsorption of malic acid on charcoal activated. Asian J Chem 17:475–480

    Google Scholar 

  27. Inci I (2004) Removal of citric acid by activated carbon adsorption. Asian J Chem 16:649–653

    Google Scholar 

  28. Inci I (2003) Adsorption equilibria of glycolic acid by activated carbon. Rev Chim 54:199–201

    Google Scholar 

  29. Madan SS, Upwanshi WA, Wasewar KL (2015) Adsorption of α-toluic acid by calcium peroxide nanoparticles, desalination and water treatment. doi:10.1080/19443994.2015.1079255

Download references

Acknowledgements

We thank ministry of Human Resource and Development (MHRD), Government of India, for the financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kailas L. Wasewar .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer International Publishing AG

About this paper

Cite this paper

Madan, S.S., Wasewar, K.L. (2017). Removal of Phenylacetic Acid from Aqueous Streams. In: Suresh, S., Kumar, A., Shukla, A., Singh, R., Krishna, C. (eds) Biofuels and Bioenergy (BICE2016). Springer Proceedings in Energy. Springer, Cham. https://doi.org/10.1007/978-3-319-47257-7_19

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-47257-7_19

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-47255-3

  • Online ISBN: 978-3-319-47257-7

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics