Skip to main content

Time-Temperature Analysis, DMA and Compression in PBXs

  • Conference paper
  • First Online:
Challenges in Mechanics of Time Dependent Materials, Volume 2

Abstract

The mechanical response of plastic-bonded explosives (PBXs) is highly complex and depends on a number of factors including, but not limited to temperature, strain rate and binders. In this work, we have measured and analyzed the mechanical properties of LX-14, which contains 95.5 wt% HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) and 4.5 wt% Estane 5702, with no additional plasticizer. We are interested to compare LX-14 with PBX 9501 (95 wt% HMX, 2.5 wt% Estane 5703 and 2.5 wt% nitroplasticizer), which has a relatively high content of plasticizer. The measurements span a wide range of strain rates and temperatures. We have applied time-temperature analysis on the LX-14 mechanical properties, i.e. dynamic mechanical analysis (DMA) measurements and quasi-static uniaxial compression to form satisfactory master curves, and these data are compared with those from PBX 9501. A unique inhomogeneity is observed in the LX-14 compression data as a function of the specimen location.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Williams, M.L., Landel, R.F., Ferry, J.D.: The temperature dependence of relaxation mechanisms in amorphous polymers and other glass forming liquids. J. Am. Chem. Soc. 77, 3701–3707 (1955)

    Article  Google Scholar 

  2. Siviour, C.R., Walley, S.M., Proud, W.G., Field, J.E.: The high strain rate compressive behaviour of polycarbonate and polvinylidine difluoride. Polymer. 46, 12546–12555 (1984)

    Article  Google Scholar 

  3. Menard, K.P.: Dynamic Mechanical Analysis, a Practical Introduction, 2nd edn. CRC Press, Taylor and Francis Group, Boca Raton (2008)

    Book  Google Scholar 

  4. Hoffman, D.M.: Dynamic mechanical signatures of a polyester-urethane and plastic bonded explosives based on this polymer. J. Appl. Polym. Sci. 83, 1009–1024 (2002)

    Article  Google Scholar 

  5. Williamson, D.M., Siviour, C.R., Proud, W.G., Palmer, S.J.P., Govier, R., Ellis, K., Blackwell, P., Leppard, C.: Temperature-time response of a polymer bonded explosive in compression (EDC 37). J. Phys. D. Appl. Phys. 41, 85404–85414 (2008)

    Article  Google Scholar 

  6. Thompson, D.G., DeLuca, R., Brown, G.W.: Time-temperature analysis of plastic-bonded explosives PBX 9501 and PBX 9502 in tension and compression. J. Energ. Mater. 30(4), 299–323 (2012). LA-UR 11-07068

    Article  Google Scholar 

  7. Olinger, B.W., Dobratz, B.M., Skidmore, C.B.: Density variations in cylinders and hemispherical shells of pressed PBX 9501 and PBX 9502. 23th aging, compatibility, and stockpile stewardship conference proceedings, Sandia National Laboratories, SAND2001-8038, CA, November 14–16, p. 133 (2000)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jamie Stull .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 The Society for Experimental Mechanics, Inc.

About this paper

Cite this paper

Thompson, D.G., Stull, J., Deluca, R., Brown, G. (2018). Time-Temperature Analysis, DMA and Compression in PBXs. In: Arzoumanidis, A., Silberstein, M., Amirkhizi, A. (eds) Challenges in Mechanics of Time Dependent Materials, Volume 2. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-63393-0_3

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-63393-0_3

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-63392-3

  • Online ISBN: 978-3-319-63393-0

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics