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Phosphate, Arsenate, Vanadate

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Mineralogie

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Zusammenfassung

Diese Mineralklasse ist wegen umfangreicher Diadochie-Möglichkeiten ganz besonders artenreich. Alle Strukturen dieser Klasse enthalten tetraedrische Anionenkomplexe [PO4]3−, [AsO4]3− und [VO4]3− als wichtigste Baueinheiten, wobei sich P5+, As5+ und V5+ diadoch vertreten können. Die Kationen sind gegenüber O [9]-koordiniert. Apatit, ihr wichtigster und häufigster Vertreter, enthält als zusätzliche Anionen 2. Stellung F, Cl und OH, die sich gegenseitig ersetzen können. Apatit-Struktur haben das Phosphat Pyromorphit, das Arsenat Mimetit und das Vanadat Vanadinit, in denen als Kation Pb2+ anstelle von Ca2+ eingebaut ist.

†Deceased

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Authors and Affiliations

  1. Lehrstuhl für Geodynamik und Geomaterialforschung Universität Würzburg, Am Hubland, 97074, Würzburg, Germany

    Professor Dr. Martin Okrusch

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  1. Professor Dr. Martin Okrusch
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  2. Professor Dr. Siegfried Matthes †
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Okrusch, M., Matthes †, S. (2010). Phosphate, Arsenate, Vanadate. In: Mineralogie. Springer-Lehrbuch. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-78201-8_8

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