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Study of Selective Adsorption of Gases by Calorimetry

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Calorimetry and Thermal Methods in Catalysis

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 154))

Abstract

This chapter is devoted to the study of coadsorption of gases in nanoporous solids by using the differential calorimetry. In the first part, the thermodynamic principles of adsorption of gases are recalled. Some of them have already presented in chapter one. However a special attention has been paid here to the determination of the adsorption enthalpies and entropies and we focused on the selective adsorption of binary mixtures. Then the specific experimental technique based on the combination of differential calorimetry with manometry and gas phase chromatography or mass spectrometry is shown in details. In the last part, the thermodynamic concepts on coadsorption are illustrated with experimental results taken from studies on gas separation by selective adsorption in microporous solids.

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References

  1. S.J. Gregg, K.S.W. Sing, Adsorption, Surface Area and Porosity (Academic Press, London, 1982)

    Google Scholar 

  2. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemienewska, Pure Appl. Chem. 57(4), 603 (1985)

    Article  CAS  Google Scholar 

  3. F. Rouquerol, J. Rouquerol, K. Sing, Adsorption by Powders and Porous Solids (Academic Press, London, 1999)

    Google Scholar 

  4. R.M. Barrer, Zeolites and clay minerals as sorbents and molecular sieves (Academic Press, New York, 1978)

    Google Scholar 

  5. F. Thibault-Starzyk, M.H. Simonot-Grange, Les matériaux micro et mésoporeux—Caractérisation (EDP Sciences, Les Ulis, 2004)

    Google Scholar 

  6. P.W. Atkins, Physical Chemistry (Oxford University Press, Oxford, 1990)

    Google Scholar 

  7. D.D. Do, Adsorption Analysis: Equilibria and Kinetics (Imperial College Press, London, 1998)

    Google Scholar 

  8. M.H. Simonot-Grange, O. Bertrand, E. Pilverdier, J.P. Bellat, C. Paulin, J. Thermal Anal. 48, 741 (1997)

    Article  CAS  Google Scholar 

  9. V. Cottier, J.P. Bellat, M.H. Simonot-Grange, A. Méthivier, J. Phys. Chem. B 101(24), 4798 (1997)

    Article  CAS  Google Scholar 

  10. S. Sircar, J. Chem. Soc. Faraday Trans. 1 81, 1527 (1985)

    Google Scholar 

  11. S. Ross, J.P. Olivier, On Physical Adsorption (Interscience Publishers John Wiley & Sons, New York USA, 1964)

    Google Scholar 

  12. A. Boutin, G. Dosseh, A. Fuchs, Eléments de Thermodynamique (Masson, Paris, 1997)

    Google Scholar 

  13. D.B. Broughton, R.W. Neuzil, J.M. Pharis, C.S. Breatly, Chem. Eng. Prog. 66(9), 70 (1970)

    CAS  Google Scholar 

  14. R.T. Yang, Gas separation by adsorption processes (Imperial College Press, London, 1987)

    Google Scholar 

  15. G. Hotier, B. Balannec, Revue de l’Institut Français du Pétrole 46, 803 (1991)

    CAS  Google Scholar 

  16. D.W. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974)

    Google Scholar 

  17. C. Beauvais, A. Boutin, A.H. Fuchs, Chem. Phys. Chem. 5, 1791 (2004)

    Article  CAS  Google Scholar 

  18. C. Beauvais, A. Boutin, A.H. Fuchs, C.R. Chimie 8, 485 (2005)

    Google Scholar 

  19. V. Cottier, E. Pilverdier, M.H. Simonot-Grange, J.P. Bellat, J. Thermal Anal. 58, 121 (1999)

    Article  CAS  Google Scholar 

  20. J.P. Bellat, M.H. Simonot-Grange, S. Jullian, Zeolite 15, 124 (1995)

    Article  CAS  Google Scholar 

  21. J.P. Bellat, M.H. Simonot-Grange, Zeolite 15, 219 (1995)

    Article  CAS  Google Scholar 

  22. M. Czjzek, H. Fuess, T. Vogt, J. Phys. Chem. 95, 5255 (1991)

    Article  CAS  Google Scholar 

  23. C. Mellot, M.H. Simonot-Grange, E. Pilverdier, J.P. Bellat, D. Espinat, Langmuir 11(5), 1727 (1995)

    Article  Google Scholar 

  24. V. Lachet, A. Boutin, B. Tavitian, A. Fuchs, J. Phys. Chem. 102, 9224 (1998)

    CAS  Google Scholar 

  25. V. Lachet, S. Buttefey, A. Boutin, A. Fuchs, Phys. Chem. Chem. Phys. 3, 80 (2001)

    Article  CAS  Google Scholar 

  26. V. Cottier, J.P. Bellat, M.H. Simonot-Grange, J. Phys. Chem. B 101(24), 4798 (1997)

    Article  CAS  Google Scholar 

  27. J.C. Moïse, J.P. Bellat, J. Phys. Chem. B 109, 17239 (2005)

    Article  Google Scholar 

  28. G. Weber, J.P. Bellat, F. Benoit, C. Paulin, S. Limborg-Noetinger, M. Thomas, Adsorption 11, 183 (2005)

    Article  Google Scholar 

  29. G. Weber, F. Benoit, J.P. Bellat, C. Paulin, P. Mougin, M. Thomas, Microporous Mesoporous Mater. 109, 184 (2008)

    Article  CAS  Google Scholar 

  30. F. Benoit, G. Weber, J.P. Bellat, C. Paulin, P. Mougin, M. Thomas, Adsorption 14, 501 (2008)

    Article  Google Scholar 

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Authors and Affiliations

  1. Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR 6303 CNRS-Université de Bourgogne, 9 avenue A. Savary, BP 47870, 21078 , Dijon, France

    Jean-Pierre Bellat

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  1. Jean-Pierre Bellat
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Correspondence to Jean-Pierre Bellat .

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Editors and Affiliations

  1. Lyon (IRCELYON), Institut de Recherches sur la Catalyse et l’Environnement de, Villeurbanne CX, France

    Aline Auroux

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Bellat, JP. (2013). Study of Selective Adsorption of Gases by Calorimetry. In: Auroux, A. (eds) Calorimetry and Thermal Methods in Catalysis. Springer Series in Materials Science, vol 154. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-11954-5_7

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