Abstract
During the last decade, the occurrence of persistent organic pollutants (POPs) has drawn great attention because of their high rates of production and consumption, their considerable environmental persistence, toxic potential, high levels of bioaccumulation and harmful biological effects including their mutagenic and carcinogenic properties (Fernández and Grimalt 2003). Important groups of POPs include: polycyclic aromatic hydrocarbons (PAHs) and halogenated hydrocarbons such as organchlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) (Ritter et al. 1995). Because of their hydrophobicity and resistance to degradation, they are widely distributed in the various components of the environment (Potrykus et al. 2003). The atmosphere has been regarded as the major pathway for the global distribution of POPs (Koziol and Pudykiewicz 2001). Consequently, the characterization of POPs in air has been subjected to intensive study world-wide in order to assess their environmental fate and human exposure (Liu et al. 2005).
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References
AOAC (2002) Association of Analytical Communities (AOAC) guidelines for single laboratory validation of chemical methods
Bi X, Sheng G, Peng P, Chen Y, Zhang Z, Fu J (2003) Distribution of particulate- and vapor-phase n-alkanes and polycyclic aromatic hydrocarbons in urban atmosphere of Guangzhou. China Atmos Environ 37:289–298
Bidleman TF (1988) Atmospheric process wet and dry deposition of organic compounds are controlled by their vapor-particle partitioning. Environ Sci Technol 22:361–367
Björklund E, Bøwadt S, Nilsson T, Mathiasson L (1999) Pressurized fluid extraction of polychlorinated biphenyls in solid environmental samples. J Chromatogr A 836:285–293
Braun T, Navratil JD, Farag AB (1986) Polyurethane foam sorbents in separation science. CRC Press, Boca Raton, FL
Chee KK, Wong MK, Lee HK (1997) Microwave-assisted solvent extraction of air particulates for the determination of PAHs. Environ Monit Assess 44:391–408
Christensen A, Ostman C, Westerholm R (2005) Ultrasound-assisted extraction and on-line LC-GC-MS for determination of polycyclic aromatic hydrocarbons (PAH) in urban dust and diesel particulate matter. Anal Bioanal Chem 381:1206–1216
Cortazar E, Bartolome L, Delgado A, Etxebarria N, Fernandez LA, Usobiaga A, Zuloaga O (2005) Optimisation of microwave-assisted extraction for the determination of nonylphenols and phthalate esters in sediment samples and comparison with pressurised solvent extraction. Anal Chim Acta 534:247–254
Duinker JC, Bruchertall F (1989) On the distribution of atmospheric polychlorinated congeners between vapor, aerosols, and rain. Environ Sci Technol 23:57–62
Fernández P, Grimalt JO (2003) On the global distribution of persistent organic pollutants. CHIMIA 57:514–521
Fisher JA, Scarlett MJ, Stott AD (1997) Accelerated solvent extraction: an evaluation for screening of soils for selected US EPA semivolatile organic priority pollutants. Environ Sci Technol 31:1120–1127
García I, Ignacio M, Mouteira A, Cobas J, Carro N (2008) Assisted solvent extraction and ion-trap tandem mass spectrometry for the determination of polychlorinated biphenyls in mussels. Comparison with other extraction techniques. Anal Bioanal Chem 390:729–737
Harner T, Shoeib M, Diamond M, Stern G, Rosenberg B (2004) Using passive air samplers to assess urban-rural trends for persistent organic pollutants. 1. Polychlorinated biphenyls and organochlorine pesticides. Environ Sci Technol 38:4478–4483
Harrad S, Mao H (2004) Atmospheric PCBs and organochlorines pesticides in Birmingham, UK: concentrations, sources, temporal and seasonal trends. Atmos Environ 38:1437–1445
Hawthorne SB, Krieger MS, Miller DJ (1989) Supercritical carbon dioxide extraction of polychlorinated biphenyls, polycyclic aromatic hydrocarbons, heteroatom-containing polycyclic aromatic hydrocarbons, and n-alkanes from polyurethane foam sorbents. Anal Chem 61:736–740
Hawthorne SB, Trembley S, Moniot CL, Grabanski CB, Miller DJ (2000) Static subcritical water extraction with simultaneous solid-phase extraction for determining polycyclic aromatic hydrocarbons on environmentals solids. J Chromatogr A 886:237–244
Hubert A, Wenzel KD, Manz M, Weissflog L, Engewald W, Scheuermann G (2000) High extraction efficiency for POPs in real contaminated soil samples using accelerated solvent extraction. Anal Chem 72:1294–1300
Iwata H, Tanabe S, Sakai N, Tatsukawa R (1993) Distribution of persistent organochlorines in the oceanic air and surface seawater and the role of ocean on their global transport and fate. Environ Sci Technol 27:1080–1098
Jaward TM, Zhang G, Nam JJ, Sweetman AJ, Obbard JP, Kobara Y, Jones KC (2005) Passive air sampling of polychlorinated biphenyls, organochlorine compounds, and polybrominated diphenyl ethers across Asia. Environ Sci Technol 39:8638–8645
Karthikeyan S, Balasubramanian R, See SW (2006) Optimization and validation of a low temperature microwave-assisted extraction method for analysis of polycyclic aromatic hydrocarbons in airborne particulate matter. Talanta 69:79–86
Koziol AS, Pudykiewicz JA (2001) Global-scale environmental transport of persistent organic pollutants. Chemosphere 45:1181–1200
Lammel G, Ghim Y-S, Grados A, Gao H, Hühnerfuss H, Lohmann R (2007) Levels of persistent organic pollutants in air in China and over the Yellow Sea. Atmos Environ 41:452–464
Lee SC, Ho KF, Chan LY, Zielinska B, Chow CJ (2001) Polycyclic aromatic hydrocarbons (PAHs) and carbonyl compounds in urban atmosphere of Hong Kong. Atmos Environ 35:5949–5960
Lenicek J, Sekyra M, Bednarkova K, Benes I, Sipek F (2000) Short term temperature dependent air–surface exchange and atmospheric concentrations of polychlorinated naphthalenes and organochlorine pesticides. Environ Sci Technol 34:393–398
Li K, Landriault M, Fingas M, Llompart M (1998) Pressurised solvent extraction of environmental organic compounds in soils using a supercritical fluid extractor. Analusis 26:365–369
Liu XH, Bi XH, Mai BX, Sheng GY, Fu JM (2005) Separation of PAHs in aerosol by thin layer chromatography for compound-specific stable carbon isope analysis. Talanta 66:487–494
Mandalakis M, Tsapakis M, Tsoga A, Stephanou EG (2002) Gas-particle concentrations and distribution of aliphatic hydrocarbons, PAHs, PCBs and PCDD/Fs in the atmosphere of Athens (Greece). Atmos Environ 36:4023–4035
Park JS, Wade TL, Sweet S (2001) Atmospheric deposition of organochlorine contaminants to Galveston Bay, Texas. Atmos Environ 35:3315–3324
Piñeiro-Iglesias M, Grueiro-Noche G, Lopez-Mahía P, Muniategui-Lorenzob S, Prada-Rodríguez D (2004) Assessment of methodologies for airborne BaP analysis. Sci Total Environ 334–335:377–384
Potrykus J, Albalat A, Pempkowiak J, Porte C (2003) Content and pattern of organic pollutants (PAHs, PCBs and DDT) in blue mussels (Mytilus trossulus) from the southern Baltic sea. Oceanologia 45:337–355
Ritter L, Solomon KR, Forget J, Stemeroff M, O’Leary C (1995) A review of selected persistent organic pollutants (DDT, Aldrin, Dieldrin, Endrin, Chlordane, Heptachlor, Hexachlorobenzene, Mïrex, Toxaphene, Polychlorinated biphenyls, Dioxins and Furans). In: International programme on chemical saftey (ICPS), p 39
Saim N, Dean JR, Abdullah MP, Zakaria Z (1998) An experimental design approach for the determination of polycyclic aromatic hydrocarbons from highly contaminated soil using accelerated solvent extraction. Anal Chem 70:420–424
Shen J, Shao X (2005) A comparison of accelerated solvent extraction, Soxhlet extraction, and ultrasonic-assisted extraction for analysis of terpenoids and sterols in tobacco. Anal Bioanal Chem 383:1003–1008
Simcik MF, Franz TP, Zhang HX, Eisenreich SJ (1998) Gas-particle partitioning of PCBs and PAHs in the Chicago urban and adjacent coastal atmosphere: states of equilibrium. Environ Sci Technol 32:215–257
Sporring S, Bøwadt S, Svensmark B, Björklund E (2005) Comprehensive comparison of classic Soxhlet extraction with Soxtec extraction, ultrasonication extraction, supercritical fluid extraction, microwave assisted extraction and accelerated solvent extraction for the determination of polychlorinated biphenyls in soil. J Chromatogr A 1090:1–9
Sun HW, Li JG (2005) Availability of pyrene in unaged and aged soils to earthworm uptake, butanol extraction and SFE. Water Air Soil Pollut 166:353–365
Tao S, Cui YH, Cao J, Xu FL, Dawson R, Li BG (2002) Determination of PAHs in wastewater irrigated agricultural soil using accelerated solvent extraction. J Environ Sci Health B37:141–150
Wang J, Guo L, Li J, Zhang G, Lee CSC, Li X, Jone KC, Xiang Y, Zhong L (2007) Passive air sampling of DDT, chlordane and HCB in the Pearl River Delta, South China: implications to regional sources. J Environ Monit 9:582–588
Wurl O, Obbard JP (2005) Organochlorine compounds in the marine atmosphere of Singapore. Atmos Environ 39:7207–7216
Wurl O, Potter JR, Obbard JP, Durville C (2006) Persistent organic pollutants in the equatorial atmosphere over the open Indian Ocean. Environ Sci Technol 40:1454–1461
Yang JS, Lee DW, Lim H (2003) Microwave-assisted extraction (MAE) of polychlorinated biphenyls and polychlorinated dibenzo-p-dioxins from fly ash and sea sediments: effect of water and removal of interferences. J Liq Chromatogr Rel Technol 26:803–818
Yeo HG, Choi M, Chun MY, Sunwoo Y (2003) Concentration distribution of polychlorinated biphenyls and organochlorine pesticides and their relationship with temperature in rural air of Korea. Atmos Environ 37:3831–3839
Yeo HG, Choi M, Chun MY, Kim TW, Cho KC, Sunwoo Y (2004) Concentration characteristics of atmospheric PCBs for urban and rural area, Korea. Sci Total Environ 324:261–270
Yusà V, Coscollà C, Mellouki W, Pastor A, de la Guardia M (2009) Sampling and analysis of pesticides in ambient air. J Chromatogr A 1216:2972–2983
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Balasubramanian, R., He, J. (2010). Trace Analysis of Persistent Organic Pollutants in the Air Using Accelerated Solvent Extraction. In: Zereini, F., Wiseman, C. (eds) Urban Airborne Particulate Matter. Environmental Science and Engineering(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-12278-1_7
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