Abstract
Methoxyamines and ethoxyamines are the simplest hetero compounds with two hetero atoms of oxygen and nitrogen. The thermodynamic properties are known for a small number of these acyclic and cyclic compounds; however, one is interested in the diversity of the realized types of specific interactions in their condensed condition. Shifting of the electron density at the carbon atoms of the methyl groups leads to an insignificant negative charge [1–3], reducing the positive value as a result of the intermolecular reverse dative bond [4–8]
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Baev, A.K. (2014). Specific Intermolecular Interactions of Methoxyamines, Methoxynitriles, and Amides. In: Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-37472-2_6
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DOI: https://doi.org/10.1007/978-3-642-37472-2_6
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