Abstract
A large number of chromotropic phenomena in solutions have also been observed and reported for transition metal complexes not covered in the foregoing chapters. In this Chapter we shall concentrate ourselves on several representative examples in which systematic studies led to a reasonably clear-cut understanding of the phenomena. It is interesting to note that the concepts of DN and AN, or of related polarity parameters, appear again and again as unifying principles in many of these examples; it is a proof of their general validity in explaining the changes that occur in solution.
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References
Cf. e.g. Goodwin, H.A.: Coord. Chem. Rev. 18, 293 (1976)
Chum, H.L. et al.: Inorg. Chem. 21, 1146 (1982)
Matsumoto, N. et al.: Chem. Lett. 1984, 479
For a study on binuclear Fe(III) complexes, see: Ohta, S. et al.: Bull. Chem. Soc. Jpn. 59,155 (1986)
Sone, K.: Bull. Chem. Soc. Jpn. 25, 1 (1952)
Krumholz, P.: J. Am. Chem. Soc. 75, 2163 (1953)
Busch, D.H., Bailer, J.C. Jr.: Am. Chem. Soc. 78, 1137 (1956)
Krumholz, P.: “Structure and Bonding”, Vol.9, p. 139 (1971)
Yamasaki, K.: Bull. Chem. Soc. Jpn. 15, 461 (1940)
Schilt, A.A.: J. Am. Chem. Soc. 82, 3000 (1960)
Schilt, A.A.: ibid. 82, 5779 (1960)
Soukup, R. W.: Chem. in unserer Zeit 17, 129 (1983)
Soukup, R. A., Schmid, R.: J. Chem. Educ. 62, 459 (1985)
Mayer, U.: Pure Appl. Chem. 51, 1697 (1979)
Taura, T.: Chem. Lett. 1984, 2011
Burgess, J.: Spectrochim. Acta 26A, 1369 (1970)
Burgess, J.: ibid. 26A, 1957 (1970)
Burgess, J.: J. Organometall. Chem. 19, 218 (1969)
Toma, H. E., Takasugi, M. S.: J. Soln. Chem. 12, 547 (1983)
Macholdt, H.-T. et al.: Inorg. Chim. Acta 104, 115 (1985)
Selbin, J., Ortolano, T. R.: J. Inorg. Nucl. Chem. 26, 37 (1964)
Selbin, J.: Chem. Rev. 65, 168 (1965)
Gutmann, V., Mayer, U.: Monatsh. Chem. 99, 1383 (1968)
Dodge, R.P. et al.: J. Chem. Phys. 35, 55 (1961)
Soukup, R. W.: Chem. in unserer Zeit 17, 163 (1983)
Ibne-Rosa, K. M.: J. Chem. Educ. 44, 89 (1967)
Gutmann, V.: “Coordination Chemistry in Non-Aqueous Solutions”, Springer, Wien (1968), p. 22
Adachi, N. et al.: Bull. Chem. Soc. Jpn. 50, 401 (1977)
Nakada, S. et al.: Chem. Lett. 1977, 1243
Yamada, M. et al.: ibid. 1978, 1153
Nakada, S. et al.: Bull. Chem. Soc. Jpn. 52, 766 (1979)
Nakada, S. et al.: ibid. 53, 2252 (1980)
Nakada, S. et al.: ibid. 54, 2913 (1981)
Chavan, M.Y. et al: Inorg. Chem. 25, 314 (1986)
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Sone, K., Fukuda, Y. (1987). Miscellaneous Chromotropic Phenomena Observed in Solutions of Metallic Complexes. In: Inorganic Thermochromism. Inorganic Chemistry Concepts, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-51017-5_5
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DOI: https://doi.org/10.1007/978-3-642-51017-5_5
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