Skip to main content

Occurrence And Trends of Pollution in the Arctic Troposphere

  • Conference paper
Chemical Exchange Between the Atmosphere and Polar Snow

Part of the book series: NATO ASI Series ((ASII,volume 43))

Abstract

The chemical composition of the troposphere (0 to ~8 km above msl) in the Arctic is distinctly different than it is in the Antarctic. As pointed out in previous reviews (Barrie, 1986; Barrie et al, 1992; Barrie, 1993; Barrie, 1995), the Arctic is surrounded by populated continents from which pollution is released to the atmosphere and is transported readily to the north. In contrast, the Antarctic region is entirely surrounded by the southern Pacific ocean and is remote from human activities. Thus, it comes as no surprise that the tropospheric concentration of many anthropogenic aerosols and gases is much higher in the Arctic than in the Antarctic. What may be less obvious is that atmospheric trace constitutents of natural origin are found to have a different chemical climatology in the Arctic than in the Antarctic. Substances derived from sea spray, wind blown dust, marine biogenic activity and volcanoes generally have different seasonal variations and concentrations in the Arctic compared to the Antarctic.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  • Barrie, L.A. and R.M. Hoff, 1984, The oxidation rate and residence time of sulphur dioxide in the Arctic atmosphere, Atmos. Envir., 18, 1995–2010.

    Google Scholar 

  • Barrie, L.A. and R.M. Hoff, 1985, Five years of air chemistry observations in the Canadian Arctic, Atmos. Envir. 18, 1459–1469.

    Article  Google Scholar 

  • Barrie, LA., 1985, Atmospheric particles: their physical/chemical characteristics and deposition processes relevant to the chemical composition of glaciers, Ann. Glaciog. 7, 100–108.

    Google Scholar 

  • Barrie, L.A., 1986, Arctic air pollution: an overview of current knowledge, Atmos. Environ., 20, 643–663.

    Article  Google Scholar 

  • Barrie, LA., J.W. Bottenheim, R.C. Schnell, P.J. Crutzen and RA. Rasmussen, 1988, Ozone destruction and photochemical reactions at polar in the lower Arctic atmosphere, Nature, 334, 138–141.

    Article  Google Scholar 

  • Barrie, LA. and M.L Barrie, 1990, Chemical components of lower tropospheric aerosols in the high Arctic: Six years of observations, J. Atmos. Chem., 11, 211–226.

    Article  Google Scholar 

  • Barrie, LA., J.W. Bottenheim, R.C. Schnell, P.J. Crutzen and RA. Rasmussen, 1988, Ozone destruction and photochemical reactions at polar in the lower Arctic atmosphere, Nature, 334,138–141.

    Article  Google Scholar 

  • Barrie L.A. and J.W. Bottenheim, 1991, Sulphur and nitrogen pollution in the Arctic atmosphere, Chapt.6, 155–184, in Ed. W. Sturges, Pollution of the Arctic Atmosphere, Elsevier Press, pp334.

    Google Scholar 

  • Barrie, L.A., 1991, Snow formation and processes in the atmosphere that influence its chemical composition, NATO ASI Series, Vol. G28, Seasonal Snowpacks, Ed. T. Davies. et al., 1–20.

    Google Scholar 

  • Barrie, LA, D. Gregor, B. Hargrave, R. Lake, D. Muir, R. Shearer, B.Tracey and T. Bidleman, 1992, Arctic contaminants: sources, occurrence and pathways, Sci. of the Total Envir., 122, 1–74.

    Article  Google Scholar 

  • Barrie, L.A., 1993, Features of polar regions relevant to tropospheric ozone chemistry, in the Tropospheric Chemistry of Ozone in the Polar Regions, eds. H. Niki and K.H. Becker, Springer Verlag, 3–24.

    Google Scholar 

  • Barrie, L.A., S.M. Li, D.L. Toom, S. Landsberger and W. Sturges, 1994a, Lower tropospheric measurements of halogens, nitrates and sulphur oxides by denuder and filter systems during Polar Sunrise Experiment 1992, J. Geophys. Res. D., 99,25453–25469.

    Article  Google Scholar 

  • Barrie, L.A., R. Staebler, D. Toom, B. Georgi, G. den Hartog, S. Landsberger, D.Wu, 1994b, Arctic aerosol size-segregated chemical observations in relation to ozone depletion during Polar Sunrise Experiment 1992, J. Geophys. Res. D., 99, 25439–25453.

    Article  Google Scholar 

  • Barrie L.A., 1995, Arctic aerosols: composition sources and transport, NATO Advanced Studies Workshop on Ice Core Studies of Global Biogeochemical Cycles, Ed. R.Delmas, NATO ASI Series 1: Global Environmental Change, 30, 1–23, Springer Verlag, Berlin, New York.

    Google Scholar 

  • Barrie L.A. and A. Sirois, 1995, Arctic aerosols trends at Alert Canada: 1980 to 1993, Atmos. Envir., submitted.

    Google Scholar 

  • Bidleman, T.F., L.M. Jantunen, R.L. Falconer, L.A. Barrie and P. Fellin, 1995, Decline of hexachlorocyclohexane in the arctic atmosphere and reversal of air-sea gas exchange, Geophys. Res. Lett., 22, 219–222.

    Article  Google Scholar 

  • Blanchet J. P. and Girard E., 1995, Water vapour feedback in the formation of continental Arctic air: its implications for climate, Sci. Tot. Environ., 160/161, 793–802.

    Article  Google Scholar 

  • Bodhaine, B.A. and E.G. Dutton, 1993, Long-term decrease in Arctic haze at Barrow Alaska. Geophys. Res. Lett., 20, 947–950.

    Article  Google Scholar 

  • Bottenheim, J.W., L.A. Barrie, E. Atlas, LE. Heidt, H. Niki, R.A. Rasmussen and P.B. Shepson, 1990, Depletion of lower tropospheric ozone during Arctic Spring: The polar sunrise experiment 1988, J. Geophys. Res., 9, 101.

    Google Scholar 

  • Bottenheim J.W., L.A. Barrie and E. Atlas, 1993, The partitioning of nitrogen oxides in the lower Arctic troposphere during spring 1988, J. Atmos. Chem.,17, 15–27.

    Article  Google Scholar 

  • Bottenheim J.W., L.A. Barrie and A. Sirios, 1994, Analysis of seven years of continuous observations of peroxyacetyl nitrate (PAN) at the high Arctic station Alert, paper #225, Joint meeting on global atmospheric chemistry, CACGP/IGAC, Fuji-Yoshida, 5–9 Sept 1994.

    Google Scholar 

  • Boutron, C.F., U. Görlach, J.P. Candelone, M.A. Bolshov and R.J. Delmas, 1991, Decrease in anthropogenic lead, cadmium and zinc in Greenland snows since the late 1960’s, Nature, 353, 153–157.

    Article  Google Scholar 

  • Bradley, R.S., FT. Keimig and H.F. Diaz, 1992 Climatology of surface-based inversions in the North American Arctic, J. Geophys. Res., 97, 15699–15712.

    Google Scholar 

  • Charlson, R.J., S.E. Schwartz, J.M. Hales, R.D. Cess, J.A. Coakley, J.E. Hansen and D.J. Hofman, 1992, Climate forcing by anthropogenic aerosols, Science, 255, 423–430.

    Article  Google Scholar 

  • Dibb, J.E., L.D. Meeker, R.C. Finkel, J.R. Southon, M.W. Caffee and L.A. Barrie, 1994, Estimation of stratospheric input to the Arctic troposphere: 7Be and 10Be in aerosols at Alert, Canada, J. Geophys. Res, 99D, 12855–12864.

    Article  Google Scholar 

  • EPRI, 1994, Mercury Atmospheric Processes Synthesis Report, EPRI/TR-104214, Proc. Workshop in Tampa Florida, Sept. 1994.

    Google Scholar 

  • Franzén L.G., M. Hjlemroos, P. Kållberg, E. Brorström-Lunden, S. Juntto and A.-L. Savolainen, 1994, The ‘yellow snow’ episode of northern fenoscandia, March 1991 — a case study of long-distance transport of soil, pollen and stable organic compounds, Atmos. Envir., 28, 3587–3605.

    Article  Google Scholar 

  • Fellin, F., L.A. Barrie, D. Dougherty, D. Toom, D. Muir, B. Grift, L. Lockhart and B. Billeek, 1995, Air monitoring in the Arctic: selected results for OC and PAH compounds for 1992, Envir. Toxic and Chem. J., in press.

    Google Scholar 

  • Hopper J.F., D.E.J. Worthy, L.A. Barrie and NBA. Trivett, 1994, Atmospheric observations of aerosi black carbon, carbon dioxide, and methane in the high Arctic, Atmos. Envir. 28, 3047–3054.

    Article  Google Scholar 

  • Hillamo R.E., V.-M. Kerminen, W. Maenhaut, J.-L. Jaffrezo, S. Balachandra and C.I. Davidson, 1993, Size distributions of atmospheric trace elements at Dye3 Geenland-I. Distribution characteristics and dry deposition velocities., Atmos. Envir., 27A, 2787–2803.

    Google Scholar 

  • Jaffe D.A. and M.D. Zukowski, 1993, Nitrate deposition to the Alaskan snowpack, Atmos. Envir., 27, 2935–2934.

    Google Scholar 

  • Jaffrezo, J.L., P. Masclet, M.P. Clain, H. Wortham, S. Beyne and H. Cachier, 1993, Transfer function of polycyclic aeromatic hydrocarbons from the atmosphere to the polar ice-l. Determination of atmospheric concentrations at Dye 3, Greenland, Atmos. Envir., 27A, 2781–2786.

    Google Scholar 

  • Jobson, B.T., H. Niki, Y. Yokouchi, J. Bottenheim, F. Hopper, R. Leaitch, 1994, Measurements of C2–C6 Hydrocarbons During the Polar Sunrise 92 Experiment, J. Geophys. Res. 99D, 25355–25368.

    Article  Google Scholar 

  • Kahl J.D., M.C. Serreze, R.S. Stone, S. Shitani, M. Kisley, and R. C. Schnell, 1993a, Tropospheric temperature trends in the Arctic, J. Geophys. Res., 98D, 12825–12838.

    Article  Google Scholar 

  • Kahl J.D., D.J. Charlevoix, N.A. Zaitseva, R.C. Schnell and M.C. Serreze, 1993b, Absence of evidence for greenhouse warming over the Arctic Ocean, Nature, 236, 335–337.

    Article  Google Scholar 

  • Kawamura, K., H. Kasukabe and L. A. Barrie, 1995a, Concentration changes of total organic carbon and nitrogen, water soluble organic carbon, and polar organic compounds in the arctic aerosols at polar sunrise,Atmos. Envir., 29, submitted.

    Google Scholar 

  • Kawamura, K., H. Kasukabe and L. A. Barrie, 1995b, Production of dicarboxylic acids in the arctic atmosphere at polar sunrise, Geophys. Res. Lett., 22,1253–1256.

    Article  Google Scholar 

  • Kinlock D., H. Kuhnlein, and D.C.G. Muir, 1992, Inuit foods and diet: a preliminary assessment of benefits and risks, Sci. Tot. Envir. 122, 247–278.

    Article  Google Scholar 

  • Li S.M. and L.A. Barrie, 1993, Biogenic sulphur aerosols in the Arctic troposphere: I Contributions to sulphate, J. Geophys. Res., 98D, 20613–20622.

    Article  Google Scholar 

  • Li S.M., L.A. Barrie and S. Sirois, 1993, Biogenic sulphur aerosols in the Arctic troposphere, J. Geophys. Res. 98D, 20623–20631.

    Article  Google Scholar 

  • Li S.M., R.W. Talbot, L.A. Barrie, R.C. Harriss, C.I. Davidson and J.-L. Jaffrezo, 1993, Seasonal and geographic variations of methane sulphonic acid in the arctic troposphere, Atmos. Envir. 27A, 3011–3024.

    Google Scholar 

  • Lindqvist, O.1994, Atmospheric cycling of mercury: an overview, 181–185 in Mercury Pollutiomlntegration and Synthesis, Eds. Watras and Huckabee, Lewis Publishers.

    Google Scholar 

  • Lockhart, W.L., 1993, Depositional trends: lake and marine sediments, pp 46–56, Synopsis of Research Conducted Under 1992/1993 Northern Contaminants Program, Eds. Murray and Shearer, DIAND ISBN 0-662-21037-9, Ottawa, Canada.

    Google Scholar 

  • Mackay, D. and F. Wania, 1995, Transport of contaminants to the Arctic: partitioning, processes and models, Sci. Tot. Environ., 160/161, 25–38.

    Article  Google Scholar 

  • Maenhaut, W., G. Ducastel and J.M. Pacyna, 1993, Atmospheric aerosol at Ny Alesund, during winter 1989: multielement composition, receptor modelling and comparision with data from previous winters, in Proc. of 5th Int. Symp. on Arctic Air Chem, 8–10 Sept. Copenhagen, NERI Tech. Rep. 70, Danish Min. of Envir. P.O Box 358, Frederiksborgvej 399, DK-4000 Roskilde, Denmark

    Google Scholar 

  • Mayewski, P.A., L.D. Meeker, M.C. Morrison, M.S. Twickler, S. Whitlow, K.K. Ferland, M.R. Legrand, and J.P. Steffenson, 1993, Greenland ice core “signal”characteristics offer expanded view of climate change, J. Geophys. Res., 98, 12839–12847.

    Article  Google Scholar 

  • Mosher B.W., P. Winkler and J.L. Jaffrezo, 1993, Seasonal aerosol chemistry at Dye3, Greenland, Atmos. Envir., 27A, 2761–2773.

    Google Scholar 

  • Muthuramu, M., P.B. Shepson, J.W. Bottenheim, BT. Jobson, H. Niki, K.G. Anlauf, 1994, Relationships between organic nitrates and surface ozone destruction during Polar Sunrise Experiment 1992, J. Geophys. Res., 99, 25369–25378.

    Article  Google Scholar 

  • Mylona S., 1993, Trends of sulphur dioxide emissions, air concentrations and depositions of sulphur in Europe since 1880, EMEP/MSC-W Rep. #2/93, The Norweg. Met. Instit., P.O. Box 43-Blindern, N-0313 Oslo 3, Norway.

    Google Scholar 

  • Niki H. and K.-H. Becker, 1993, The Tropospheric Chemistry Of Ozone In The Polar Regions, NATO ASI Series l:Global Environmental Change, Vol. 7, Springer Verlag, 425 pp.

    Google Scholar 

  • Otlmans S.J. 1993, Climatology of Arctic and Antarctic tropospheric ozone, in The Tropospheric Chemistry Of Ozone In The Polar Regions, eds Niki and Becker, NATO ASI Series liGlobal Environmental Change, Vol. 7, Springer Verlag, 25–40.

    Google Scholar 

  • Patton G.W., M.D. Walla, T.F. Bidleman and L.A. Barrie, 1991, Polycyclic aromatic and organochlorine compounds in the atmosphere of northern Ellesmere Island, Canada, J. Geophys. Res., 96D, 10867–10877.

    Article  Google Scholar 

  • Prospero J.M., D.L. Savoie, R. Arimoto, H. Olafson, and H. Hjartarson, Sources of aerosol nitrate and non-sea salt sulphate in the iceland region, Sci. Tot Environ., 160/161, 181–192.

    Google Scholar 

  • Restelli G. and G. Angelletti, 1993, Dimethylsulphide: Oceans, Atmosphere and Climate, Kluwer Acad. Pub., Dordrecht, 399 pp.

    Google Scholar 

  • Rudolph J., A. Khedim, T. Clarkson and D. Wagenbach, 1992, Long term measurements of light alkanes and acetylene in the Antarctic troposphere, Tellus, 44B, 252–261.

    Google Scholar 

  • Schroeder W. H. R. Ebinghaus, M.Shoeib , K. Timoschenko and L. A. Barrie, 1995, Atmospheric mercury measurements in the northern hemisphere from 56° to 82.5° N latitude, Water Air Soil Poll, 80: 1227–1236.

    Article  Google Scholar 

  • Slemr, F. and E. Langer, 1992, Increase in global atmospheric concentrations of mercury inferred from measurements over the Atlantic Ocean, Nature, 355, 434–437.

    Article  Google Scholar 

  • Solberg S., O. Hov, N. Schmidbauer, A. Semb and F. Stordal, 1995, Tropospheric ozone depletion in the Norwegian Arctic in spring, J. Atmos. Chem. Submitted May 1995 (NILU rep U-93093).

    Google Scholar 

  • Staebler, R.M., G. den Hartog, B. Georgi and T. Düsterdiek, 1994, Aerosol size distributions during the Polar Sunrise Experiment 1992, J. Geophys. Res, 99D, 25429–25439.

    Article  Google Scholar 

  • Stern G., L. Barrie, P. Fellin and D. Muir, 1995, Polychlorinated biphyenls in air in the high Arctic: 1992–1993, Envir. Sci. Techn., submitted.

    Google Scholar 

  • Sturges W.T. and L.A. Barrie, 1988, Chlorine, bromine and iodine in Arctic aerosols, Atmos. Envir., 22, 1179–1194.

    Article  Google Scholar 

  • Tarasick D. W., D.J. Wardle, J.B. Kerr, J.J. Bellefleur and J. Davies, 1995, Tropospheric ozone trends over Canada: 1980–1993, Geophys. Res. Lett., 22, 409–412.

    Article  Google Scholar 

  • Welch H.E., D.C.G. Muir, B.N. Billeck, W.L. Lockhart, G.J. Brunskill, H.J.KIing, M.P. Olson and R.M. Lemoine, 1991, Brown snow: a long range transport event in the Canadian Arctic, Envir. Sci. and Tech., 25, 280–286.

    Article  Google Scholar 

  • Worthy D.E.J., N.B.A. Trivett, J.F. Hopper, J.W. Bottenheim and I. Levin, Analysis of long range transport events at Alert, Northwest Territiories, during Polar Sunrise Experiment 1992, J. Geophys. Res., 99D, 25329–25344.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Barrie, L.A. (1996). Occurrence And Trends of Pollution in the Arctic Troposphere. In: Wolff, E.W., Bales, R.C. (eds) Chemical Exchange Between the Atmosphere and Polar Snow. NATO ASI Series, vol 43. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61171-1_5

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-61171-1_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64730-7

  • Online ISBN: 978-3-642-61171-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics