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Study of the Electrical Double Layer at the Interface Between Two Immiscible Electrolyte Solutions by Impedance Measurements

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The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids

Abstract

In the first theoretical approach to the interface between two immiscible electrolyte solutions (ITIES) by Verwey and Messen [1], the interface was represented by a diffuse double layer, i.e. one phase containing an excess of the positive space charge and the other phase an equal excess of the negative space charge. The space charge regions have been treated by the Gouy-Chapman theory [2, 3]. Gavach et al. [4] have suggested that the two space charge regions are separated by an inner or compact layer of oriented solvent molecules — a modified Verwey-Niessen (MVN) model. The inner layer can be either free of ions or the ions are located in the inner layer as specifically adsorbed particles. Boguslavsky et al. [5,6] and Joos and Vanden Bogaert [7] neglected the diffuse double layer and assumed an ionic monolayer or bilayer at the ITIES formed by the specifically adsorbed ions.

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Authors
  1. Zdeněk Samec
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  2. Vladimir Mareček
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Editor information

Editors and Affiliations

  1. A.N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Leninsky Prospect, 31, SU-117071, Moscow V-71, USSR

    Vladimir E. Kazarinov

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© 1987 Springer-Verlag Berlin, Heidelberg

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Samec, Z., Mareček, V. (1987). Study of the Electrical Double Layer at the Interface Between Two Immiscible Electrolyte Solutions by Impedance Measurements. In: Kazarinov, V.E. (eds) The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71881-6_7

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  • DOI: https://doi.org/10.1007/978-3-642-71881-6_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-71883-0

  • Online ISBN: 978-3-642-71881-6

  • eBook Packages: Springer Book Archive

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