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Synthesis and Properties of Some Characteristic Elastomers

  • Conference paper
Progress in Pacific Polymer Science

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Abstract

Along our studies, three sorts of characteristic elastomers are described in this review focusing on their synthesis, structure and properties.

  1. (1)

    A novel moisture-curable rubber and a high performance lignin-reinforced rubber with good processability were obtained by using newly developed 1-chloro-1,3-butadiene — 1,3-butadiene rubber (CB-BR) derived from the copolymerization of 1-chloro-l,3-butadiene (CB) and 1,3-butadiene by emulsion process.

  2. (2)

    The ionene-type viologen elastomers having poly(butadiene-co-acrylonitrile) (NBV) were obtained by the reaction of α,α’-dichloro-p-xylene (DCX), 4,4’-bipyridine (BP) and dimethylamine-terminated liquid nitrile rubber (AT-NBR). The tensile properties of these elastomers were found to depend upon the number of cation-site in a structural unit of the ionene, and to attain 46 MPa in tensile strength and 340% in elongation at break without any reinforcement and vulcanization.

  3. (3)

    Two sorts of ABA type liquid crystalline elastomers terminated with mesogenic groups were synthesized. The polymeric segment of B is polyolefin with molecular weight of about 2500. Mesogenic groups of A carring two or three phenylene groups combined by ester linkage, were prepared by the reaction of terephthalic acid and p-hydroxybenzoic acid. These polymers were liquid crystalline and could be formed into elastic films. Their thermal and mechanical properties were clarified.

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Author information

Authors and Affiliations

  1. Fuculty of Engineering and Design, Kyoto Instisute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

    S. Yamashita

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  1. S. Yamashita
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Editor information

Editors and Affiliations

  1. Central Research & Development Department, E. I. du Pont de Nemours & Company, Experimental Station, P.O. Box 80328, Wilmington, DE, 19880-0328, USA

    B. C. Anderson

  2. Department of Polymer Chemistry, Kyoto University, Kyoto 606, Japan

    Y. Imanishi

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© 1991 Springer-Verlag Berlin Heidelberg

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Yamashita, S. (1991). Synthesis and Properties of Some Characteristic Elastomers. In: Anderson, B.C., Imanishi, Y. (eds) Progress in Pacific Polymer Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84115-6_31

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  • DOI: https://doi.org/10.1007/978-3-642-84115-6_31

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84117-0

  • Online ISBN: 978-3-642-84115-6

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