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Time-Resolved Resonance Raman Spectroscopy of the Excited States of Ru(II) Complexes with Novel Polynucleating Ligands

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Time-Resolved Vibrational Spectroscopy V

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 68))

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Abstract

For more than a decade transient resonance Raman spectroscopy using pulsed laser excitation has been an established technique[1] for probing the excited states of metal complexes, though there are relatively few reports of true time-resolved resonance Raman (TR3) studies involving two lasers in a pump-delayed probe arrangement. Some recent examples are listed [2,3]. We have used such two laser methods on the nanosecond timescale to investigate the decay processes following metal-ligand charge-transfer (MLCT) excitation of some heteroleptic complexes of Ru(II) with the novel ligand 1,4,5,8,9,12-hexaazatriphenylene (HAT) and either 2,2′-bipyridyl (bpy), 1,4,5,8-tetraazaphenanthrene (TAP) or 1,10-phenanthroline (phen).

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References

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Author information

Authors and Affiliations

  1. School of Chemistry, The Queen’s University of Belfast, Belfast, BT9 SAG, Northern Ireland

    S. E. J. Bell, K. C. Gordon, J. J. McGarvey & D. I. C. Martin

  2. Faculté des Sciences, Université Libre de Bruxelles, CP 160, B-1050, Bruxelles, Belgium

    A. Kirsch-de Mesmaeker & J.-P. Lecomte

Authors
  1. S. E. J. Bell
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  2. K. C. Gordon
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  3. J. J. McGarvey
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  4. D. I. C. Martin
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  5. A. Kirsch-de Mesmaeker
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  6. J.-P. Lecomte
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Editor information

Editors and Affiliations

  1. Department of Chemistry, School of Science & Engineering, Waseda University, Tokyo 169, Japan

    Hiroaki Takahashi

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© 1992 Springer-Verlag Berlin Heidelberg

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Bell, S.E.J., Gordon, K.C., McGarvey, J.J., Martin, D.I.C., Kirsch-de Mesmaeker, A., Lecomte, JP. (1992). Time-Resolved Resonance Raman Spectroscopy of the Excited States of Ru(II) Complexes with Novel Polynucleating Ligands. In: Takahashi, H. (eds) Time-Resolved Vibrational Spectroscopy V. Springer Proceedings in Physics, vol 68. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84771-4_33

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  • DOI: https://doi.org/10.1007/978-3-642-84771-4_33

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84773-8

  • Online ISBN: 978-3-642-84771-4

  • eBook Packages: Springer Book Archive

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