Abstract
Negative ions of copper clusters reacted with nitric oxide molecules are studied by mass-selected photoelectron spectroscopy. The series of the reacted cluster ions, Cu n N− Cu n NO−, and Cu n NO −2 are observed in the mass spectrum. Photoelectron spectra are obtained at 3.49 eV photon energy for Cu n N− (n = 2 and 3) and Ca n NO −2 (n = 1 and 2). The photoelectron spectrum of Cu2N− contains a band structure analogous to that of Cu− or Cu −2 . From the expansion gas pressure dependence of the band peak intensity in the spectrum, it is concluded that Cu2N− has at least two isomers in the beam. One of the isomers is expected to have a structure in which the central ion is Cu− or Cu −2 and the residual atom(s) are weakly bound to the ion. For Cu n NO− (n = 1 − 3), we detected no electron signals with the detachment photon energy of 3.49 eV. The possible structure of CuNO− is discussed in the light of the present results and also on the basis of the recent results of the study of CuO −2 by Wang and coworkers.
Preview
Unable to display preview. Download preview PDF.
References
J. Koutecky, P. Fantucchi: Chem. Rev. 86, 539 (1986)
M.D. Morse: Chem. Rev. 86, 1049 (1986)
M.L. Cohen, M.Y. Chou, W.D. Knight, W.A. de Heer: J. Phys. Chem. 91, 3141 (1987)
M.M. Kappes: Chem. Rev. 88, 369 (1988)
W.A. de Heer: Rev. Mod. Phys. 65, 611 (1993)
H. Haberland (Ed.): Clusters of Atoms and Molecules I, Springer Ser. in Chern. Phys. 52 ( Springer. Berlin 1994 )
R.L. Whetten, D.M. Cox, D.J. Trevor, A. Kaldor: Phys. Rev. Lett. 54, 1494 (1985)
J. Conceicao, R.T. Laaksonen, L.-S. Wang, T. Guo, P. Nordlander, R.E. Smalley: Phys Rev. B 51, 4668 (1995)
M.A. Nygren, REM. Siegbahn, C. Jin, T. Guo, R.E. Smalley: J. Chem. Phys. 95, 6181 (1991)
M.A. Nygren. P.E.M. Siegbahn: J. Phys. Chem. 96, 7579 (1992)
L. Holmgren, H. Gronbeck, M…A.ndersson, A. Rosen: Phys. Rev. B 53, 16644 (1996)
H. Gronbeck, A. Rosen: Surf. Rev. Lett 3, 687 (1996)
P. Bague, K. Hermann, C.W. Bauschlicher, Jr.: J. Chem. Phys. 81, 1966 (1984)
K. Hermann, P.S. Bague, C.J. Nelin: Phys. Rev, B 35. 9467 (1987)
A. Rochefort, R. Fournier: J. Phys. Chem. 100. 13, 506 (1996)
C.-Y. Cha, G. Ganteför, W. Eberhardt: Ber. Bunsenges. Phys. Chem. 96, 1223 (1992)
H. Handschuh, G. Schulze Icking-Konert, G. Ganteför, P.S. Bechthold, W. Eberhardt: Surf. Rev. Lett. 3, 643 (1996)
H. Wu, S.R. Desai, L.-S. Wang: J. Chem. Phys. 103, 4363 (1995)
S.R. Decal, H. Wu, C.M. Rohlfing, L.-S. Wang: J. Chem. Phys. 106, 1309 (1997)
H. Wu, L.-S. Wang: J. Chem. Phys. 107, 16 (1997)
H. Wu, L.-S. Wang: J. Chern. Phys. 107, 8221 (1997)
M. Shelef: Chem. Rev. 95, 209 (1995)
M.H. Matloob, M.W. Roberts: J. Chem. Soc. Faraday Trans: I 73, 1393 (1977)
D.W. Johnson, M.H.Matloob, M.W. Roberts: J. Chem. Soc., Chem. Comm. 40 (1978)
D.W. Johnson, iil, H, Matioob, M.W. Roberts: J. Cham Soc. Faraday Trans. I 75, 2143 (1979)
P. Kruit, F.H. Read: J. Phys. E 16, 313 (1983)
O. Cheshnovsky, S.H. Yang, C.L. Pettiette, M.J. Craycraft, R.E. Smalley: Rev. Sci. Instrurn. 58, 2131 (1987)
H. Handschuh, G. Ganteför, W. Eberhardt: Rev. Sci. In-strum. 66, 3838 (1995)
D.G. Leopold, J. Ho, V.T.C. Lineberger: J. Chem. Phys. 86, 1715 (1987)
M.D. Morse, M.E. Geusic, J.R. Heath, R.E. Smalley: J. Chem. Phys. 83, 2293 (1985)
J. Ho, K.M. Ervin, W.C. Lineberger: J. Chem. Phys. 93, 6987 (1990)
G. Gantefbr, M. Gansa, K.-H. Meiwes-Broer, H.O. Lutz: J. Chem. Soc, Faraday Trans. 86, 2483 (1990)
C.-Y, Cha, G. Ganteför, W. Eberhardt: J. Chem. Phys. 99, 6308 (1993)
H. Hotop, W.C. Lineberger: J. Chem. Phys. 58, 2379 (1973)
H. Hotop, R.A. Bennett, W.C. Lineberger: ibid. 58, 2373 (1973)
H. Hotop, W.C. Lineberger: J. Phys. Chem. Ref. Data 14, 731 (1985)
M.W. Siegel, R.J. Celotta, JL. Han, J. Levine, R.A. Bennett: Phys. Rev. A 6, 607 (1972)
R.J. Celotta, R.A. Bennett, J.L. Hall, M.W. Siegel, J. Levine: Phys. Rev. A 6, 631 (1972)
K.M. Ervin, J. Ho, W.C. Lineberger: Phys. Chem. 92, 5405 (1988)
S.B. Woo, E.M. Hehrty, P.H. Mauk. A.P. Paszek: Phys. Rev. A 24. 1380 (1981)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer-Verlag Italia
About this paper
Cite this paper
Misaizu, F., Furuhashi, M., Takada, A., Yamakita, Y., Ohno, K. (1999). Negative-ion photoelectron spectroscopy of Cu clusters reacted with NO molecules. In: Châtelain, A., Bonard, JM. (eds) The European Physical Journal D. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-88188-6_56
Download citation
DOI: https://doi.org/10.1007/978-3-642-88188-6_56
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-88190-9
Online ISBN: 978-3-642-88188-6
eBook Packages: Springer Book Archive