Abstract
Calculations within the independent-electron approximation are often a prerequisite for those which include correlation effects. The assumption of independently moving electrons implies that the total wavefunction of the N-electron system Φ( r 1σ1, …, r N σ N ) can be written in the form of an antisymmetrized product of single-electron wavefunctions ϕ( r i σ i ).
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Chapter 2
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© 1991 Springer-Verlag in Berlin Heidelberg
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Fulde, P. (1991). The Independent-Electron Approximation. In: Electron Correlations in Molecules and Solids. Springer Series in Solid-State Sciences, vol 100. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-97309-3_2
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DOI: https://doi.org/10.1007/978-3-642-97309-3_2
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