Abstract
Previous work has shown that metal complexes in the presence of Lewis acids may lead to: (i) simple addition of the Lewis acid to unshared electron pairs of coordinated ligands (3), (ii) Lewis acid addition to unshared electron pairs of a metal (2, 4) and (iii) more complex reactions (1). This report covers some of our recent experiments designed to explore (i) — simple ligand basicity.
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References
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The compounds in which X = H or F have been reported previously in ref. 3b.
We have not yet characterized the compound in parenthesis.
This work was supported by the N.S. F. and by the Advanced Research Projects Agency of the Department of Defense through the Northwestern Materials Research Center.
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Shriver, D.F., Luntz, A., Rupp, J.J. (1964). Interaction of Lewis Acids with Transition Metal Complexes. In: Gutmann, V. (eds) Proceedings of the 8th International Conference on Coordination Chemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-3650-8_120
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DOI: https://doi.org/10.1007/978-3-7091-3650-8_120
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