Abstract
In the previous two chapters, iron-catalyzed synthesis of fused aromatics via C–H bond activation was developed. Although the reaction proceeds under mild conditions, the use of an unstable Grignard reagent is a practical disadvantage from the viewpoint of synthetic chemistry. Therefore, the reaction using an aryl bromide under reductive conditions instead of using Grignard reagents was envisioned to develop more practical iron-catalyzed reactions.
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Matsumoto, A. (2014). Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium. In: Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation. Springer Theses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54928-4_4
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DOI: https://doi.org/10.1007/978-4-431-54928-4_4
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