Abstract
The electrocatalytical carboxylation of some perfluoroalkylhalides and α,ω-dihaloperfluoroalkanes on copper and stainless steel electrodes in near- and supercritical CO2 — methanol mixtures have been investigated. The main products and intermediates were determinated. It was shown that the difference in the composition of products in these two cases indicates at quite different catalytic activity of copper and stainless steel electrodes as to regards the electroreduction reaction of the intermediates and quite different adsorption of these intermediates on the surface of the electrodes.
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References
P. Calas, A. Commeyras, J. Electroanal.Chem. 1978, 89, 363.
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© 1998 Springer Japan
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Mazin, V.M., Sterlin, S.R., Grinberg, V.A. (1998). Electroreduction of Dihaloperfluoroalkanes and Perfluoroalkylhalides in Near-Critical and Supercritical CO2 -Methanol Medium. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_87
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DOI: https://doi.org/10.1007/978-4-431-65924-2_87
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-65926-6
Online ISBN: 978-4-431-65924-2
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