Abstract
This review is intended to provide both a concise overview of the chemistry of hydroperoxides and dialkylperoxides and a glimpse of newer topics not discussed in previous literature. Following a brief discussion of safety matters, the initial section discusses perhaps the most widely known aspect of peroxide chemistry, reactions involving homolytic or heterolytic cleavage of the peroxide bond. A section covering nonradical methods for hydroperoxide functionalization is followed by a discussion of the reactions of peroxyl radicals. The review concludes with a traditionally overlooked area: the successful use of hydroperoxides and peroxides as stable synthetic intermediates.
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References
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Dussault, P. (1995). Reactions of Hydroperoxides and Peroxides. In: Foote, C.S., Valentine, J.S., Greenberg, A., Liebman, J.F. (eds) Active Oxygen in Chemistry. Structure Energetics and Reactivity in Chemistry Series (SEARCH Series), vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0874-7_5
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