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Solvation Dynamics and Ultrafast Electron Transfer

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Perspectives in Photosynthesis

Part of the book series: The Jerusalem Symposia on Quantum Chemistry and Biochemistry ((JSQC,volume 22))

Abstract

Ultrafast fluorescence spectroscopy has been used to study two processes: (i) the transient solvation of electronically excited coumarin probes and (ii) the solvent mediated excited state intramolecular electron (charge) transfer of 9,9′—bianthryl and related compounds. The solvation measurements have been analyzed in terms of contemporary theory to gain insight on the molecular aspects of microscopic motion in polar liquids. The excited state electron transfer (et) examples are well modeled by an electronically adiabatic approach, employing an “outer sphere” generalized Langevin equation description of motion along the et reaction coordinate. The relationship between solvation and electron transfer dynamics is discussed.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Minnesota, Minneapolis, Minnesota, 55455, USA

    Paul F. Barbara, Tai Jong Kang & Włodzimięrz Jarzeba

  2. Department of Chemistry, Colorado State University, Fort Collins, Colorado, 80523, USA

    Teresa Fonseca

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  1. Paul F. Barbara
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  2. Tai Jong Kang
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  3. Włodzimięrz Jarzeba
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  4. Teresa Fonseca
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Editor information

Editors and Affiliations

  1. Department of Chemistry, University of Tel-Aviv, Israel

    J. Jortner

  2. Institut de Biologie Physico-Chimique (Fondation Edmond de Rothschild), Paris, France

    B. Pullman

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© 1990 Kluwer Academic Publishers

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Barbara, P.F., Kang, T.J., Jarzeba, W., Fonseca, T. (1990). Solvation Dynamics and Ultrafast Electron Transfer. In: Jortner, J., Pullman, B. (eds) Perspectives in Photosynthesis. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 22. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0489-7_21

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  • DOI: https://doi.org/10.1007/978-94-009-0489-7_21

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