Abstract
In this Chapter a number of organic reactions are discussed which are catalysed under homogeneous conditions by complexes of the transition elements. A few of these, notably the carbonylation of methanol to yield acetic acid and the conversion of alkenes into aldehydes or alcohols with carbon monoxide and hydrogen (hydroformylation) are used industrially on a large scale. Most industrial catalysts, however, are heterogeneous, that is, they do not belong to the same phase as the reactants. Normally a catalyst is a solid, often a highly dispersed metal or a metal oxide with a high surface area and reactions take place on adsorption of reactant molecules at its surface.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
General texts
Atwood, J.D. (1985) Mechanisms of Inorganic and Organometallic Reactions, Brooks/Cole, CA.
Bond, G. C. (1987) Heterogeneous Catalysis, Principles and Applications, 2nd Edn, Oxford University Press, Oxford.
Masters, C. (1981) Homogenenou Transition-Metal Catalysis—a gentle art, Chapman and Hall, London.
Parshall, G.W. (1980) Homogeneous Catalysis, Wiley-Interscience, New York.
Somorjai, G.A. (1981) Chemistry in Two Dimensions, Cornell University Press, Ithaca, NY.
Industrial applications
Pearce, C. and Patterson, W. (Eds) (1981) Catalysis and Industrial Processes, Leonard Hall, Glasgow.
Wiseman, P. (1979) An Introduction to Industrial Organic Chemistry, 2nd Edn, Applied Science, London.
Specific processes Hydrocyanation
Tolman, C.A. (1986) J. Chem. Educ., 63, 199.
Dimerization
Su, A.C.L. (1979) Adv. Organomet. Chem., 17, 269.
Bogdanovic, B. (1979) Adv. Organomet, Chem., 17, 105.
Oligomerization of Butadiene
Jolly, P.W. (1985) Angew. Chem. (Int. Edn), 24, 283. Comprehensive Organometallic Chemistry, Ch. 56.4.
Ziegler-Natta Catalysis
Eisch, J.J. (1983) J. Chem. Educ., 60, 1009.
Pino, P. and Mulhaupt, R. (1980) Angew. Chem. (Int. Edn), 19, 857.
Ziegler, K. (1967) Adv. Organomet. Chem., 6, 1.
Olefin Metathesis
Banks, R.L. (1979) Chem. Tech., 494; (1986), Chem. Tech., 112.
Calderon, N., Lawrence, J.P., Ofstead, E.A. (1979) Adv. Organomet. Chem., 17, 449.
Katz, T.J. (1978) Adv. Organomet. Chem., 16, 283.
Mol, J.C. (1983) Chem. Tech., 250.
Schrock, R.R. (1983) Science, 219, 13; (1986) J. Organomet. Chem., 300, 249.
Streck, R. (1983) Chem. Tech., 758.
Wacker
Backvall, J.E. (1983) Acc. Chem. Res., 16, 335.
Hydroformylation
Pruett, R.L. (1979) Adv. Organomet. Chem., 17, 1.
Fischer-tropsch
Henrici-Olivé, G. and Olivé, S. (1984) The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide, Springer Verlag, Berlin.
Herrmann, W.A. (1982) Angew. Chem. (Int. Edn), 21, 117.
Syn. Gas
Forster, D. (1979) Adv. Organomet Chem., 17, 255.
King, D.L. and Grate, J.H. (1985) Chem. Tech., 244.
Maugh, T.H., II (1983) Science, 220, 1032.
Supported Metal Catalysts
Bailey, D.C. and Langer, S.H. (1981) Chem. Revs., 81, 109.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1988 P. Powell
About this chapter
Cite this chapter
Powell, P. (1988). Mechanisms of industrial processes clarified by studies of homogeneous catalysis by complexes of transition elements. In: Principles of Organometallic Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1197-0_12
Download citation
DOI: https://doi.org/10.1007/978-94-009-1197-0_12
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7032-4
Online ISBN: 978-94-009-1197-0
eBook Packages: Springer Book Archive