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Magic-Angle Spinning

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Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications

Part of the book series: NATO ASI Series ((ASIC,volume 322))

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Abstract

The magic-angle spinning experiment is described and its use with cross-polarization to obtain high-resolution spectra of dilute spins is discussed, with examples. Spectral editing by dipolar dephasing is presented. The occurrence of spinning sidebands and their analysis are reviewed. Several experiments using two-dimensional methods with magic-angle spinning are described, particularly for the study of chemical exchange and/or spin diffusion.

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References

  1. A general, applications-oriented, account of these studies is given in C.A. Fyfe, Solid State NMR for Chemists, CFC Press. 1984.

    Google Scholar 

  2. T.M. Duncan and C.R. Dybowski, Surface Science Reports, 1. 157 (1981).

    Article  CAS  Google Scholar 

  3. E.R. Andrew, A. Bradbury and R.G. Eades, Nature, 182, 1659 (1958).

    Article  CAS  Google Scholar 

  4. E.R. Andrew, A. Bradbury and R.G. Eades, Nature, 183, 1802 (1959).

    Article  CAS  Google Scholar 

  5. I.J. Lowe, Phys. Rev. Lett., 2, 285 (1959).

    Article  CAS  Google Scholar 

  6. E.R. Andrew, Internat. Rev. Phys. Chem., 1, 195 (1981).

    Article  CAS  Google Scholar 

  7. F.D. Doty, P.D. Ellis, Rev. Sci. Instrum., 52, 1868 (1981).

    Article  Google Scholar 

  8. J. Schaefer, E.O. Stejskal, J. Amer. Chem. Soc., 98, 1031 (1976).

    Article  CAS  Google Scholar 

  9. C.A. Fyfe, G.C. Gobbi, J.S. Hartman, R.E. Lenkinski, J.H. O’Brien, E.R. Beange, M.A.R. Smith, J. Magn. Reson., 47, 168 (1982).

    CAS  Google Scholar 

  10. C.A. Fyfe, J.R. Lyerla, C.S. Yannoni, Acc. Chem. Res., 15, 208 (1982).

    Article  Google Scholar 

  11. E. Kundla, A. Samoson, E. Lippmaa, Chem. Phys. Lett., 83, 229 (1981).

    Article  CAS  Google Scholar 

  12. A. Samoson, E. Kundla, E. Lippmaa, J. Magn. Reson., 49, 350 (1983).

    Google Scholar 

  13. E. Oldfield, R.A. Kinsey, B. Montey, T. Ray, K.A. Smith, J. C. S. Chem. Commun., 254 (1982).

    Google Scholar 

  14. M.D. Meadows, K.A. Smith, R.A. Kinsey, T.M. Rothgeb, R.P. Skarjunl, E. Oldfield, Proc. Natl. Acad. Sci. USA, 79, 1351 (1982).

    Article  CAS  Google Scholar 

  15. C.A. Fyfe, H. Mossbruger, C.S. Yannoni, J. Magn. Reson., 36, 61 (1979).

    CAS  Google Scholar 

  16. P. Myhre, C.S. Yannoni, J. Amer. Chem. Soc., 103, 230 (1981).

    Article  CAS  Google Scholar 

  17. R.L. Dudley, C.A. Fyfe, Fuel, 61, 651 (1982).

    Article  CAS  Google Scholar 

  18. S.J. Opella, M.H. Frey, J. Amer. Chem. Soc., 101, 5854 (1979).

    Article  CAS  Google Scholar 

  19. R.F. Childs, B.D. Dickie, R. Faggiani, C.A. Fyfe, C.J.L. Lock, R.E. Wasylishen to be published.

    Google Scholar 

  20. J. Schaefer, E.O. Stejskal, R.A. McKay, J. Magn. Reson., 25, 269 (1977).

    Google Scholar 

  21. E. Lippmaa, M. Alla, T. Tuherm, XIX Congress Ampere, Heidelberg. (1976).

    Google Scholar 

  22. J. Herzfeld, A.E. Berger, J. Chem. Phys., 73, 6021 (1980).

    Article  CAS  Google Scholar 

  23. W.T. Dixon, J. Magn. Reson., 44, 220 (1981).

    CAS  Google Scholar 

  24. W.T. Dixon, J. Chem. Phys., 77, 1800 (1982).

    Article  CAS  Google Scholar 

  25. W.T. Dixon, J. Schaefer, M.D. Sefcik, E.O. Stejskal, R.A. McKay, J. Magn. Reson., 49, 341 (1982).

    CAS  Google Scholar 

  26. M.M. Maricq, J.S. Waugh, J. Chem. Phys., 70, 3300 (1979).

    Article  CAS  Google Scholar 

  27. N.J. Clayden, C.M. Dobson, L. Lian, D.J. Smith, J. Magn. Reson.. 69, 476 (1986).

    CAS  Google Scholar 

  28. R.K. Harris, L.H. Merwin, G. Hägele, J.C.S. Faraday 1, 85, 1409 (1989).

    Article  CAS  Google Scholar 

  29. Bai Haiping, R.K. Harris and A. Sebald, unpublished work.

    Google Scholar 

  30. I.J. Cox, Ph.D. Thesis, University of East Anglia (1984).

    Google Scholar 

  31. P. Jackson, Ph.D. Thesis, University of Durham (1987).

    Google Scholar 

  32. J. Schraml, J.M. Bellama, Two-dimensional NMR spectroscopy, Wiley-Interscience (1988).

    Google Scholar 

  33. N.M. Szeverenyi, M.J. Sullivan, G.E. Maciel, J. Magn. Reson., 47, 462 (1982).

    CAS  Google Scholar 

  34. J. Jeener, B.H. Meier, P. Bachmann, R.R. Ernst, J. Chem. Phys.. 71, 4546 (1979).

    Article  CAS  Google Scholar 

  35. P. Caravatti, J.A. Deli, G. Bodenhausen, R.R. Ernst, J. Amer. Chem. Soc., 104, 5506 (1982).

    Article  CAS  Google Scholar 

  36. S.J. Opella, M.H. Frey, J. Amer. Chem. Soc., 106, 4942 (1984).

    Article  Google Scholar 

  37. D.L. VanderHart, J. Magn. Reson., 72, 13 (1987).

    CAS  Google Scholar 

  38. V. Bark, J. Schaefer, J. Magn. Reson., 78, 348 (1988).

    Google Scholar 

  39. R. Benn, H. Grondey, C. Brevard, A. Pagelot, J. C. S. Chem. Commun., 102 (1988).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of British Columbia, Vancouver, British Columbia, V6T 1Y6, Canada

    Colin A. Fyfe

Authors
  1. Colin A. Fyfe
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Editor information

Editors and Affiliations

  1. Institut de Chimie, Université Louis Pasteur, Strasbourg, France

    Pierre Granger

  2. Department of Chemistry, Science Laboratories, University of Durham, Durham, UK

    Robin K. Harris

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© 1990 Kluwer Academic Publishers

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Fyfe, C.A. (1990). Magic-Angle Spinning. In: Granger, P., Harris, R.K. (eds) Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications. NATO ASI Series, vol 322. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2149-8_17

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  • DOI: https://doi.org/10.1007/978-94-009-2149-8_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7467-4

  • Online ISBN: 978-94-009-2149-8

  • eBook Packages: Springer Book Archive

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