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Hyperfine Interactions

  • Chapter
Mössbauer Spectroscopy

Abstract

It was shown in Chapter 1 that the Mössbauer effect produced monochromatic γ-radiation with a definition of the order of 1 part in 1012 and we now seek ways to use this extremely high precision to obtain chemical information. The key to the problem lies in the total interaction Hamiltonian for the atom, which contains terms relating to interactions between the nucleus on the one hand and the electrons (and hence the chemical environment) on the other. The Hamiltonian can be written as

$$ H\;{\rm{ = }}{H_0}\;{\rm{ + }}{E_0}\;{\rm{ + }}{M_1}\;{\rm{ + }}{E_2}\;{\rm{ + }}{\rm{. }}{\rm{. }}{\rm{. }} $$
(3.1)

where \( {H_0} \) represents all terms in the Hamiltonian for the atom except the hyperfine interactions being considered; E 0 refers to electric monopole (i.e. Coulombic) interactions between the nucleus and the electrons; M 1 refers to magnetic dipole hyperfine interactions; and E 2 refers to electric quadrupole interactions. Higher terms are usually negligible.

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Authors and Affiliations

  1. University of Leeds, UK

    N. N. Greenwood (Professor of Inorganic and Structural Chemistry) & T. C. Gibb (Lecturer in Inorganic and Structural Chemistry)

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  1. N. N. Greenwood
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© 1971 T. C. Gibb and N. N. Greenwood

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Greenwood, N.N., Gibb, T.C. (1971). Hyperfine Interactions. In: Mössbauer Spectroscopy. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5697-1_3

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  • DOI: https://doi.org/10.1007/978-94-009-5697-1_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-5699-5

  • Online ISBN: 978-94-009-5697-1

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