Summary
This chapter describes the application of gas chromatography to the study of solid polymers. The word ‘inverse’ is used to indicate that the component of interest is the stationary phase, which consists of polymer-coated support. Using this technique, glass transition temperatures, percentage crystal-Unities and surface areas can be obtained for the pure polymer. In addition, solution studies can be undertaken where the polymer is the concentrated ‘solvent’ and small amounts of organic vapour act as the solute or probe. Using data from these experiments, diffusion constants and solubilities can be calculated for the probe in the polymer, as well as activity coefficients, heats of solution, Flory-Huggins interaction parameters (x) and infinite dilution polymer solubility parameters. The chapter is divided into sections describing the different applications; in each section experimental details are outlined and the literature work is reviewed.
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References
Everett, D. H., Trans. Faraday Soc., 1965, 1637.
GALIN, M. and GUILLET, J. E., J. Polym. Sci., Polym. Lett. Ed., 1973, 11, 233.
Perrault, G., Tremblay, M., Bedard, M., Duchesne, G. and Voyzelle, R., Eur. Polym. J., 1974, 10, 143.
GRAY, D. G. and GUILLET, J. E., Polym. Sci., Polym. Lett. Ed., 1974, 12, 231.
Lichtenthaler, R. N., Liu, D. D. and Prausnitz, J. M., Macromolecules, 1974, 7, 565.
Laub, R. J., Purnell, J. H., Williams, P. S., Harbison, M. W. P. and Martire, D. E., J. Chromatogr., 1978, 155, 233.
Alishoev, V. R., Berezkin, V. G. and Mel’nikova, Y. V., Russ. J. Phys. Chem., 1965, 39, 105.
SMIDSROD, O. and GUILLET, J. E., Macromolecules, 1969, 2, 272.
GUILLET, J. E., New Developments in Gas Chromatography, H. Purnell, Ed., 1973, Wiley, New York.
Braun, J.-M. and Guillet, J. E., Macromolecules, 1975, 8, 882.
Lipatov, Y. S. and Nesterov, A. E., Macromolecules, 1975, 8, 889.
YAMAMOTO, Y., TSUGE, S. and TAKEUCHI, T., Bull. Chem. Soc. Jpn., 1971, 44, 1145.
Condor, J. R., Locke, D. C. and Purnell, J. H., J. Phys. Chem., 1969, 73, 700.
Nakamura, S., Shindo, S. and Matsuzaki, K., J. Polym. Sci., Part B, 1971, 9, 591.
Galassi, S. and Audisio, G., Makromol. Chem., 1974, 175, 2975.
Llorente, M. A., Menduina, C. and Horta, A., J. Polym. Sci., Polym. Phys. Ed., 1979, 17, 189.
Deshpande, D. D. and Tyagi, O. S., Macromolecules, 1978, 11, 746.
Braun, J.-M. and Guillet, J. E., J. Polym. Sci., Polym. Chem. Ed., 1976, 14, 1073.
Hayakawa, R., Nishi, T., Arisawa, K. and Wada, Y., J. Polym. Sci., Part A-2, 1967, 5, 165.
Hsiung, P. L. and Cates, D. M., J. Appi. Polym. Sci., 1975, 19, 3051.
SCHNEIDER, I. A. and CÂLUGÂRU, E.-M., Eur. Polym. J., 1977, 13, 833.
BRAUN, Jr-M. and GUILLET, J. E., Macromolecules, 1976, 9, 340.
Klein, J. and Widdecke, H., J. Chromatogr., 1978, 147, 384.
Schneider, I. A. and CǍLUGǍRU, E.-M., Eur. Polym. J., 1975, 11, 857.
Schneider, I. A. and CǍLUGǍRU, E.-M., Eur. Polym. J., 1975, 11, 861.
Schneider, I. A. and CǍLUGǍRU, E.-M., Eur. Polym. J., 1976, 12, 879.
Ito, K., Sakakura, H. and Yamashita, Y., J. Polym. Sci., Polym. Lett. Ed., 1977, 15, 755.
Ito, K., Sakakura, H., Isogai, K. and Yamashita, Y., J. Polym. Sci., Polym. Lett. Ed., 1978, 16, 21.
Ito, K., Usami, N. and Yamashita, Y., Macromolecules, 1980, 13, 216.
Deshpande, D. D., Patterson, D., Schreiber, H. P. and Su, C. S., Macromolecules, 1974, 7, 530.
Su, C. S., Patterson, D. and Schreiber, H. P., J. Appi. Polym. Sci., 1976, 20, 1025.
Olabisi, O., Macromolecules, 1975, 8, 316.
Su, C. S. and PATTERSON, D., Macromolecules, 1977, 10, 708.
Ito, K., Sakakura, H. and Yamashita, Y., J. Polym. Sci., Polym. Lett. Ed., 1977, 15, 755.
Galin, M. and Rupprecht, M. C., Macromolecules, 1979, 12, 506.
Liebman, S. A., Ahlstrom, D. H. and Foltz, C. R., Chromatogr., 1972, 67, 153.
NARDI, V., Abstracts, Am. Chem. Soc., Meeting, New York, September 1969.
Dewar, M. J. S. and Schroeder, J. P., J. Am. Chem. Soc., 1964, 86, 5235.
Gray, D. G. and Guillet, J. E., Macromolecules, 1972, 5, 316.
JAMES, D. H. and PHILLIPS, C. S. G., Chem. Soc., 1954, 1066.
Gluekauf, E., J. Chem. Soc., 1947, 1302.
DeVault, D., J. Am. Chem. Soc., 1943, 65, 532.
Kiselev, A. V., Zung, L. and Nikitin, Yu. S., Kolloid Zh., 1971, 33, 224.
BRUNAUER, S., The Adsorption of Gases and Vapors, vol. 1, 1945, Princeton University Press, Princeton, New Jersey.
CRANK, J. and PARK, G. S. (Eds), Diffusion in Polymers, 1968, Academic Press, New York.
COURVAL, G. and GRAY, D. G., Macromolecules, 1975, 8, 326.
GALIN, M. and RUPPRECHT, M. C., Polymer, 1978, 19, 506.
Mohlin, U. B. and Gray, D. G., J. Colloid Interface Sci., 1974, 47, 747.
TREMAINE, P. R. and GRAY, D. G., (a) J. Chem. Soc., Faraday I, 1975, 71, 2170;
TREMAINE, P. R. and GRAY, D. G., (b) Anal. Chem., 1976, 48, 380.
Stein, A. N. and Guillet, J. E., Macromolecules, 1970, 3, 102.
Gray, D. G. and Guillet, J. E., Macromolecules, 1971, 4, 129.
Hudec, P., Makro. Chem., 1977, 178, 1187.
Braun, J.-M. and Guillet, J. E., J. Polym. Sci., Polym. Chem. Ed., 1975, 13, 1119.
Buchdahl, R., Miller, R. L. and Newman, S., J. Polym. Sci., 1959, 36, 215.
Braun, J.-M. and Guillet, J. E., Macromolecules, 1977, 10, 101.
Van Deemter, J. J., Zuiderweg, F. J. and Klinkenberg, A., Chem. Eng. Sci., 1956, 5, 271.
GIDDINGS, J. C., Anal. Chem., 1963, 35, 439.
MILLEN, W. and HAWKES, S. J., J. Polym. Sci., Polym. Lett. Ed., 1977, 15, 463.
Gray, D. G. and Guillet, J. E., Macromolecules, 1973, 6, 223.
Gray, D. G. and Guillet, J. E., Macromolecules, 1974, 7, 244.
Liao, H.-L. and Martire, D. E., Anal. Chem., 1972, 44, 498.
BRAUN, J.-M., Poos, S. and GUILLET, J. E., J. Polym. Sci., Polym. Lett. Ed., 1976, 14, 257.
MARTIRE, D. E., Anal. Chem., 1974, 46, 626.
Patterson, D., Tewari, Y. B., Schreiber, H. P. and Guillet, J. E., Macromolecules, 1971, 4, 356.
Daola-Baranyi, G., Braun, J.-M. and Guillet, J. E., Macromolecules, 1978, 11, 224.
Aspler, J. S. and Gray, D. G., Macromolecules, 1979, 12, 562.
Kawakami, M., Egashira, M. and Kagawa, S., Bull. Chem. Soc. Jpn., 1976, 49, 3449.
Dinçer, S., and Bonner, D. C., Macromolecules, 1978, 11, 107.
DINçER, S. and BONNER, D. C., Appl. Polym. Sci., 1978, 22, 3235.
Patterson, D., Rubber Chem. Tech., 1967, 40, 1.
Blanks, R. F. and Prausnitz, J. M., Ind. Eng. Chem. Fundam., 1964, 3, 1.
Scott, R. L. and Magat, M., J. Polym. Sci., 1949, 4, 555.
Ito, K. and Guillet, J. E., Macromolecules, 1979, 12, 1163.
Orwoll, R. A. and Flory, P. J., J. Am. Chem. Soc., 1967, 89, 6814, 6822.
Orwoll, R. A. and Flory, P. J., J. Am. Chem. Soc., 1961, 86, 3507, 3515.
Tait, P. J. and Abushihada, A. M., Macromolecules, 1978, 11, 918.
Eichinger, B. E. and Flory, P. J., Trans. Faraday Soc., 1968, 64, 2035.
Patterson, D. and Robard, A., Macromolecules, 1978, 11, 690.
Brockmeier, N. F., Moy, R. W. and Meyer, J. A., Macromolecules, 1972, 5, 130.
Hammers, W. E. and De Ligny, C. L., J. Polym. Sci., Part C, 1972, 39, 273.
LEUNG, Y.-K. and EICHINGER, B. E., J. Phys. Chem., 1974, 78, 60.
HAMMERS, W. E. and DIGNY, C. L., Reel. Trav. Chim. Pays-Bas, 1971, 90, 912.
Summers, W. R., Tewari, Y. B. and Schreiber, H. P., Macromolecules, 1972, 5, 12.
Galin, M., Macromolecules, 1977, 10, 1239.
Hammers, W. E., Bos, B. C., Vaas, L. H., Loomans, Y. J. W. A. and Digny, C. L., J. Polym. Sci., Polym. Phys. Ed., 1975, 13, 401.
Hammers, W. E. and Digny, C. L., J. Polym. Sci., Polym. Phys. Ed., 1974, 12, 2065.
Brockmeier, N. F., Moy, R. W. and Meyer, J. A., Macromolecules, 1972, 5, 464.
Tewari, Y. B. and Schreiber, H. P., Macromolecules, 1972, 5, 329.
Leung, Y. K., Polymer, 1976, 17, 374.
Schreiber, H. P., Tewari, Y. B. and Patterson, D., J. Polym. Sci., Polym. Phys. Ed., 1973, 11, 15.
Daola-Baranyi, G., Guillet, J. E., Jeberien, H.-E. and Klein, J., Makromol. Chem., 1980, 181, 215.
Condor, J. R. and Purnell, J. H., Trans. Faraday Soc., 1968, 64, 1505, 3100.
Condor, J. R. and Purnell, J. H., Trans. Faradav Soc., 1969, 65, 824, 839.
Brockmeier, N. F., Carlson, R. E. and Moy, R. W., AIC J., 1973, 19, 1133.
Liu, D. D. and Prausnitz, J. M., Ind. Eng. Chem. Fundam., 1976, 15, 330.
Liu, D. D. and Prausnitz, J. M., J. Polym. Sci., Polym. Phys. Ed., 1977, 15, 145.
Durrill, P. L. and Griskey, R. G., AIC J., 1966, 12, 1147.
Lundberg, J. L. and Mooney, E. J., J. Polym. Sci., Part A-2, 1969, 7, 958.
Maloney, D. P. and Prausnitz, J. M., AIC J., 1976, 22, 74.
Sugiyama, T., Takeuchi, T. and Suzuki, Y., J. Chromatogr., 1978, 105, 265, 273.
Maloney, D. P. and Prausnitz, J. M., Ind. Eng. Chem. Process Des. Dev., 1976, 15, 216.
SMALL, P. A., J. Appl. Chem., 1953, 3, 71.
Daola-Baranyi, G. and Guillet, J. E., Macromolecules, 1978, 11, 228.
LIPSON, J. E. G. and GUILLET, J. E., J. Polym. Sci., Polym. Phys. Ed., 1981, 19, 1199.
MENDENHALL, W. and SCHAEFFER, R., Mathematical Statistics With Applications, 1973, Duxbury Press, North Scituate, Mass.
Daola-Baranyi, G., Guillet, J. E., Jeberien, H.-E. and Klein, J., J. Chromatogr., 1978, 166, 349.
Ito, K. and Guillet, J. E., Macromolecules, 1979, 12, 1163.
Hansen, C. M., J. Paint Technol., 1967, 39, 104, 505.
KUMAR, R. and PRAUSNITZ, J. M., Solutions and Solubilities, part I, M. R. Dack, Ed., 1976, Wiley-Interscience, New York.
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Lipson, J.E.G., Guillet, J.E. (1982). Study of Structure and Interactions in Polymers by Inverse Gas Chromatography. In: Dawkins, J.V. (eds) Developments in Polymer Characterisation—3. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7346-6_2
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DOI: https://doi.org/10.1007/978-94-009-7346-6_2
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