Abstract
Aqueous solutions of polyelectrolytes present a very large dielectric increment which has been recognized as originating from the polarisation of the counter-ion atmosphere. By definition, the polarizability a is linked to the partition function Q of the system through [1].
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Van Vleck, J. H.: Electric and Magnetic Susceptibilities, Oxford University Press, 1932.
Oosawa, F.: Biopolymers 9, 677 (1970).
Mandel, M.: Mol Phys. 4, 489 (1961).
A. Litzler, R., Cerf, R., and Sadron, C.: Compt. Rend Acad. Sci. 259, 473 (1964).
Benoit, H.: Ann. Phys. 6, 561 (1951).
see Mandel, M.: this volume, p. 285.
Weill, G., Hornick, C., and Stoylov, S.: J. Chim. Phys. 65, 182 (1963).
Hornick, C. and Weill, G.: Biopolymers 10, 2345 (1970).
Ullmann, R.: Macromolecules 2, 27 (1969).
Alexandrowicz, Z. and Katchalsky, A.: J. Polymer Sci. Al 3231 (1963).
Lifson, S. and Katchalsky, A.: J. Polymer Sci. 13, 43 (1964).
O’Konski, C. T.: J. Phys. Chem. 64, 605 (1960).
Schwartz, G.: Z. Physik. Chem. 19, 286 (1959).
Takashima, S.: Advances in Chem. Series 63, 232 (1967).
Daune, M.: Biopolymers 7, 659 (1969).
McTague, J. and Gibbs, J. H.: J. Chem. Phys. 44, 4295 (1966).
Minakata, A., Imai, N., and Oosawa, F.: Biopolymers 11, 347 (1972).
Oosawa, F.: Polymer Sci. 23, 421 (1957).
Schurr, M.: Biopolymers 10, 1371 (1971).
Padova, J.: J. Chem. Phys. 39, 1552 (1963).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1974 D. Reidel Publishing Company, Dordrecht-Holland
About this chapter
Cite this chapter
Weill, G., Hornick, C. (1974). Electric Polarisability of Rigid Polyelectrolytes. In: Sélégny, E., Mandel, M., Strauss, U.P. (eds) Polyelectrolytes. Charged and Reactive Polymers, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-2185-2_16
Download citation
DOI: https://doi.org/10.1007/978-94-010-2185-2_16
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-2187-6
Online ISBN: 978-94-010-2185-2
eBook Packages: Springer Book Archive