Abstract
The elucidation of the mechanisms of thermal reactions in inorganic and bioinorganic chemistry through the application of high pressure kinetic techniques is described. High pressure kinetic and thermodynamic data are used to construct volume profiles for typical reactions that include ligand substitution, activation of small molecules, and electron transfer processes. The mechanistic information obtained from such profiles is discussed in detail.
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Van Eldik, R. (1999). Inorganic and Bioinorganic Reaction Kinetics Under High Pressure. In: Winter, R., Jonas, J. (eds) High Pressure Molecular Science. NATO Science Series, vol 358. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4669-2_16
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DOI: https://doi.org/10.1007/978-94-011-4669-2_16
Publisher Name: Springer, Dordrecht
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