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Molecular Engineering of NIR Dyes

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Near-Infrared Dyes for High Technology Applications

Part of the book series: NATO ASI Series ((ASHT,volume 52))

Abstract

Structure-property relationships of conjugated organic compounds are governed by three fundamental principles, the triad principle, the energy principle, and the bonding principle, which enable chemists to design new substances with given properties. Especially color and constitution relationships are understood by five basic color rules which states that polymethine-like compounds absorb at much longer wavelengths than aromatic or polyene-like compounds of the same size. Further strong red-shift necessitates perturbation of the unique alternation of the n-electron densities in polymethines. As the intended red-shifts are compensated through aromatization and polyene formation such effects have to be excluded in molecular engineering of NIR dyes.

More quantitative estimations of structure-property relationships are achieved through long polymethine chain approximation (LPCA) which is a topological approach involving effective parameters of polymethine chain end groups, namely, the electron donor ability, the effective length, and their derivatives with respect to energy.

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Author information

Authors and Affiliations

  1. Federal Institute for Materials Research and Testing, Rudower Chaussee 5, 12587, Berlin, Germany

    Siegfried Daehne

  2. Institute of Organic Chemistry, Ukrainian Academy of Sciences, Murmanskaja Street 5, 253660, Kiev-94, Ukraine

    Marina L. Dekhtyar

Authors
  1. Siegfried Daehne
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  2. Marina L. Dekhtyar
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Editors and Affiliations

  1. Federal Institute for Materials Research and Testing, Berlin, Germany

    Siegfried Daehne  & Ute Resch-Genger  & 

  2. Institute of Analytical Chemistry, Chemo-and Biosensors, University of Regensburg, Regensburg, Germany

    Otto S. Wolfbeis

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© 1998 Springer Science+Business Media Dordrecht

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Daehne, S., Dekhtyar, M.L. (1998). Molecular Engineering of NIR Dyes. In: Daehne, S., Resch-Genger, U., Wolfbeis, O.S. (eds) Near-Infrared Dyes for High Technology Applications. NATO ASI Series, vol 52. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5102-3_17

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  • DOI: https://doi.org/10.1007/978-94-011-5102-3_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6143-8

  • Online ISBN: 978-94-011-5102-3

  • eBook Packages: Springer Book Archive

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