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The Ligand Polarization Model for the Spectra of Metal Complexes

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Optical Activity and Chiral Discrimination

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 48))

Abstract

Investigations of the optical activity of chiral metal complexes, discussed in the preceding Chapter, have the notable feature that the one-electron static-field model virtually monopolised the independent-systems approach to the problem over the two decades following the pioneer work of Moffitt [1] in 1956. In contrast, the dynamic-coupling and the staticfield methods received comparable attention in discussions of chiral organic compounds over the same period, and any bias there was lay more towards the dynamic-coupling treatment, although the two models were generally taken to be complementary.

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Mason, S.F. (1979). The Ligand Polarization Model for the Spectra of Metal Complexes. In: Mason, S.F. (eds) Optical Activity and Chiral Discrimination. NATO Advanced Study Institutes Series, vol 48. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7644-4_7

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  • DOI: https://doi.org/10.1007/978-94-015-7644-4_7

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-8355-5

  • Online ISBN: 978-94-015-7644-4

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