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Laser-Raman Spectroscopy of Some Lanthanide/Hgl2 Heterometallic Complexes (HL=5,7-Dimethyl-1,8-Naphthyridine-2-OL)

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Application of Particle and Laser Beams in Materials Technology

Part of the book series: NATO ASI Series ((NSSE,volume 283))

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Abstract

The reaction of the complex HgL2 (1) (HL = 5,7-dimethyl-1,8-naphthyridine-2-ol) with the nitrate salts of praseodymium and erbium ions yielded the heterometallic complexes with the formulae [(HgL2)2 Pr(NO3)3]n (2) and [(HgL2)3 Er2(NO3)6]n ( 3) respectively. The binding character of the ligand and the nitrate ion, as well as the metal coordination sites, have been established with spectroscopy techniques (Reflectance, FT-IR and Laser-Raman).

Work carried out during Dr. Lalia-Kantouri’s leave of absence at the Imperial College, UK.

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References

  1. Goodgame D.M.L., Khaled A.M., O’Mahoney C.A. and Williams DJ., Metallation of β-propiolactam; Crystal structures of Hg(C3H4NO)2.H2O and of the bi-metallic polymeric complex [Hg3(C3H4NO)6Er2(NO3)6]n. J. Chem. Soc, Chem. Commun. 851 (1990).

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  2. Goodgame D.M.L., Khaled A.M. and Williams DJ., Influence of lactam ring size on metallo-macrocycle ring type; Synthesis and crystal structure of the heterometallic complex [Hg2Er(C8H14(NO3)3]n, Polyhedron 10, 1079 (1991).

    Article  CAS  Google Scholar 

  3. Carrad L.H., Goodgame D.M.L., Lalia-Kantouri M. and Winsey G., Formation of some Lanthanide (III)/Mercury(II) heterometallic complexes by pyridones, Synthesis and Reactivity in Inorganic and Metallo-organic Chemistry 22, 269 (1992).

    Article  CAS  Google Scholar 

  4. Goodgame D.M.L., Lalia-Kantouri M. and Williams D.J., Crystal and molecular structures of 5,7-dimethyl-l,8-naphthyridine-2-ol (=LH) and of its mercury(II) complex HgL2 and synthesis of some lanthanide/HgL2 heterometallic complexes, Journal of Crystallographic and Spectroscopic Research 23, 577 (1993).

    Article  CAS  Google Scholar 

  5. Loader J., Basic Laser Raman Spectroscopy, Heyden & Son/ Sadtler Research Lab. Inc., London (1970).

    Google Scholar 

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© 1995 Springer Science+Business Media Dordrecht

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Lalia-Kantouri, M., Goodgame, D.M.L. (1995). Laser-Raman Spectroscopy of Some Lanthanide/Hgl2 Heterometallic Complexes (HL=5,7-Dimethyl-1,8-Naphthyridine-2-OL). In: Misaelides, P. (eds) Application of Particle and Laser Beams in Materials Technology. NATO ASI Series, vol 283. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8459-3_18

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  • DOI: https://doi.org/10.1007/978-94-015-8459-3_18

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4510-2

  • Online ISBN: 978-94-015-8459-3

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