Abstract
The reaction of the complex HgL2 (1) (HL = 5,7-dimethyl-1,8-naphthyridine-2-ol) with the nitrate salts of praseodymium and erbium ions yielded the heterometallic complexes with the formulae [(HgL2)2 Pr(NO3)3]n (2) and [(HgL2)3 Er2(NO3)6]n ( 3) respectively. The binding character of the ligand and the nitrate ion, as well as the metal coordination sites, have been established with spectroscopy techniques (Reflectance, FT-IR and Laser-Raman).
Work carried out during Dr. Lalia-Kantouri’s leave of absence at the Imperial College, UK.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Goodgame D.M.L., Khaled A.M., O’Mahoney C.A. and Williams DJ., Metallation of β-propiolactam; Crystal structures of Hg(C3H4NO)2.H2O and of the bi-metallic polymeric complex [Hg3(C3H4NO)6Er2(NO3)6]n. J. Chem. Soc, Chem. Commun. 851 (1990).
Goodgame D.M.L., Khaled A.M. and Williams DJ., Influence of lactam ring size on metallo-macrocycle ring type; Synthesis and crystal structure of the heterometallic complex [Hg2Er(C8H14(NO3)3]n, Polyhedron 10, 1079 (1991).
Carrad L.H., Goodgame D.M.L., Lalia-Kantouri M. and Winsey G., Formation of some Lanthanide (III)/Mercury(II) heterometallic complexes by pyridones, Synthesis and Reactivity in Inorganic and Metallo-organic Chemistry 22, 269 (1992).
Goodgame D.M.L., Lalia-Kantouri M. and Williams D.J., Crystal and molecular structures of 5,7-dimethyl-l,8-naphthyridine-2-ol (=LH) and of its mercury(II) complex HgL2 and synthesis of some lanthanide/HgL2 heterometallic complexes, Journal of Crystallographic and Spectroscopic Research 23, 577 (1993).
Loader J., Basic Laser Raman Spectroscopy, Heyden & Son/ Sadtler Research Lab. Inc., London (1970).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Lalia-Kantouri, M., Goodgame, D.M.L. (1995). Laser-Raman Spectroscopy of Some Lanthanide/Hgl2 Heterometallic Complexes (HL=5,7-Dimethyl-1,8-Naphthyridine-2-OL). In: Misaelides, P. (eds) Application of Particle and Laser Beams in Materials Technology. NATO ASI Series, vol 283. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8459-3_18
Download citation
DOI: https://doi.org/10.1007/978-94-015-8459-3_18
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-4510-2
Online ISBN: 978-94-015-8459-3
eBook Packages: Springer Book Archive