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Synthesis and Electrochemical Studies of a Novel MOPOF Cathode Material, [Li2(VO)2(C2O4)(HPO4)2]

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Phosphate Based Cathodes and Reduced Graphene Oxide Composite Anodes for Energy Storage Applications

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Abstract

This chapter deals with the synthesis and ab initio structure determination of a novel lithium containing Metal Organophosphate Open Framework (MOPOF) material, [Li2(VO)2(HPO4)2(C2O4)]·6H2O. It was synthesized by hydrothermal method at 120 °C and the crystal structure was solved and refined from its powder X-ray diffraction data. The anhydrous phase, [Li2(VO)2(HPO4)2(C2O4)] obtained by dehydration of the hydrated phase at 200 °C was studied as a novel cathode material for Lithium ion batteries. The presence of extractable Li+ ions in the inter-layer space together with the feasibility of V4+/V5+ redox couple and a good theoretical capacity of 125 mAh g−1 make this compound suitable as a cathode material. Electrochemical properties of the material was investigated using cyclic voltammetry, galvanostatic charge-discharge cycling, electrochemical impedance spectroscopy (EIS) and ex situ XRD studies. The material exhibits reversible lithium insertion at ~4 V with a reversible capacity of 80 mAh g−1 at 0.1 C current rate.

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References

  1. S.-Y. Chung, J.T. Bloking, Y.-M. Chiang, Nat. Mater. 1, 123–128 (2002)

    Article  Google Scholar 

  2. A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc. 144, 1188–1194 (1997)

    Article  Google Scholar 

  3. M.K. Devaraju, I. Honma, Adv. Energy Mater. 2, 284–297 (2012)

    Article  Google Scholar 

  4. T.A. Kerr, J. Gaubicher, L.F. Nazar, Electrochem. Solid-State Lett. 3, 460–462 (2000)

    Article  Google Scholar 

  5. K.H. Lii, C.H. Li, C.Y. Cheng, S.L. Wang, J. Solid State Chem. 95, 352–359 (1991)

    Article  Google Scholar 

  6. H. Huang, S.-C. Yin, T. Kerr, N. Taylor, L.F. Nazar, Adv. Mater. (Weinheim, Ger.) 14, 1525–1528 (2002)

    Google Scholar 

  7. X.H. Rui, C. Li, C.H. Chen, Electrochim. Acta 54, 3374–3380 (2009)

    Article  Google Scholar 

  8. H. Karami, F. Taala, J. Power Sources 196, 6400–6411 (2011)

    Article  Google Scholar 

  9. T. Muraliganth, K.R. Stroukoff, A. Manthiram, Chem. Mater. 22, 5754–5761 (2010)

    Article  Google Scholar 

  10. A. Nyten, A. Abouimrane, M. Armand, T. Gustafsson, J.O. Thomas, Electrochem. Commun. 7, 156–160 (2005)

    Article  Google Scholar 

  11. S.J. Kim, J. Suk, Y.J. Yun, H.-K. Jung, S. Choi, Phys. Chem. Chem. Phys. 16, 2085–2089 (2014)

    Article  Google Scholar 

  12. P. Barpanda, M. Ati, B.C. Melot, G. Rousse, J.N. Chotard, M.L. Doublet, M.T. Sougrati, S.A. Corr, J.C. Jumas, J.M. Tarascon, Nat. Mater. 10, 772–779 (2011)

    Article  Google Scholar 

  13. J.M. Clark, C. Eames, M. Reynaud, G. Rousse, J.-N. Chotard, J.-M. Tarascon, M.S. Islam, J. Mater. Chem. A 2, 7446–7453 (2014)

    Article  Google Scholar 

  14. N. Recham, J.N. Chotard, L. Dupont, C. Delacourt, W. Walker, M. Armand, J.M. Tarascon, Nat. Mater. 9, 68–74 (2010)

    Article  Google Scholar 

  15. Y. Janssen, D.S. Middlemiss, S.-H. Bo, C.P. Grey, P.G. Khalifah, J. Am. Chem. Soc. 134, 12516–12527 (2012)

    Article  Google Scholar 

  16. L. Tao, G. Rousse, J.N. Chotard, L. Dupont, S. Bruyere, D. Hanzel, G. Mali, R. Dominko, S. Levasseur, C. Masquelier, J. Mater. Chem. A 2, 2060–2070 (2014)

    Article  Google Scholar 

  17. M. Tamaru, P. Barpanda, Y. Yamada, S.-I. Nishimura, A. Yamada, J. Mater. Chem. 22, 24526–24529 (2012)

    Article  Google Scholar 

  18. S.-I. Nishimura, M. Nakamura, R. Natsui, A. Yamada, J. Am. Chem. Soc. 132, 13596–13597 (2010)

    Article  Google Scholar 

  19. J. Barker, M.Y. Saidi, J.L. Swoyer, J. Electrochem. Soc. 150, A1394–A1398 (2003)

    Article  Google Scholar 

  20. M.V. Reddy, G.V. Subba, Rao and B. V. R. Chowdari. J. Power Sources 195, 5768–5774 (2010)

    Article  Google Scholar 

  21. S.-L. Li, Q. Xu, Energy Environ. Sci. 6, 1656–1683 (2013)

    Article  Google Scholar 

  22. X. Li, F. Cheng, S. Zhang, J. Chen, J. Power Sources 160, 542–547 (2006)

    Article  Google Scholar 

  23. G. Férey, F. Millange, M. Morcrette, C. Serre, M.-L. Doublet, J.-M. Grenèche, J.-M. Tarascon, Angew. Chem. Int. Ed. 46, 3259–3263 (2007)

    Article  Google Scholar 

  24. G. de Combarieu, M. Morcrette, F. Millange, N. Guillou, J. Cabana, C.P. Grey, I. Margiolaki, G. Ferey, J.M. Tarascon, Chem. Mater. 21, 1602–1611 (2009)

    Article  Google Scholar 

  25. K. Saravanan, M. Nagarathinam, P. Balaya, J.J. Vittal, J. Mater. Chem. 20, 8329–8335 (2010)

    Article  Google Scholar 

  26. M. Nagarathinam, K. Saravanan, E.J.H. Phua, M.V. Reddy, B.V.R. Chowdari, J.J. Vittal, Angew. Chem. Int. Ed. 51, 5866–5870 (2012)

    Article  Google Scholar 

  27. J.F. Colin, T. Bataille, S.E. Ashbrook, N. Audebrand, L. Le Pollès, J.Y. Pivan, E. Le Fur, Inorg. Chem. 45, 6034–6040 (2006)

    Article  Google Scholar 

  28. F.R. Kizewski, P. Boyle, D. Hesterberg, J.D. Martin, J. Am. Chem. Soc. 132, 2301–2308 (2010)

    Article  Google Scholar 

  29. C.-Y. Sheu, S.-F. Lee, K.-H. Lii, Inorg. Chem. 45, 1891–1893 (2006)

    Article  Google Scholar 

  30. S. Natarajan, S. Mandal, Angew. Chem. Int. Ed. 47, 4798–4828 (2008)

    Article  Google Scholar 

  31. I.C. Madsen, R.J. Hill, J. Appl. Cryst. 27, 385–392 (1994)

    Article  Google Scholar 

  32. A. Coelho, J. Appl. Cryst. 36, 86–95 (2003)

    Article  Google Scholar 

  33. R.W. Cheary, A. Coelho, J. Appl. Cryst. 25, 109–121 (1992)

    Article  Google Scholar 

  34. R.W. Cheary, A.A. Coelho, J. Appl. Cryst. 31, 862–868 (1998)

    Article  Google Scholar 

  35. C. Scheringer, Acta Crystallogr. 16, 546–550 (1963)

    Article  Google Scholar 

  36. H. Rietveld, J. Appl. Cryst. 2, 65–71 (1969)

    Article  Google Scholar 

  37. W. Dollase, J. Appl. Cryst. 19, 267–272 (1986)

    Article  Google Scholar 

  38. M. Bianchini, J.M. Ateba-Mba, P. Dagault, E. Bogdan, D. Carlier, E. Suard, C. Masquelier, L. Croguennec, J. Mater. Chem. A 2, 10182–10192 (2014)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry and Earth Sciences, Qatar University, Doha, Qatar

    Abdulrahman Shahul Hameed

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  1. Abdulrahman Shahul Hameed
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Correspondence to Abdulrahman Shahul Hameed .

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Hameed, A.S. (2016). Synthesis and Electrochemical Studies of a Novel MOPOF Cathode Material, [Li2(VO)2(C2O4)(HPO4)2]. In: Phosphate Based Cathodes and Reduced Graphene Oxide Composite Anodes for Energy Storage Applications. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-2302-6_3

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  • DOI: https://doi.org/10.1007/978-981-10-2302-6_3

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-10-2301-9

  • Online ISBN: 978-981-10-2302-6

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