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Efficient and Economical Application of a Spent Waste Adsorbent Cu2+-Loaded Poly (AAc-AM-SH) Superabsorbent Hydrogels by Reusing It for Adsorption of Phosphate Ion

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Water Quality Management

Part of the book series: Water Science and Technology Library ((WSTL,volume 79))

Abstract

In the present study, a more potential and economical method is described to reutilize a waste adsorbent as the waste Cu2+-loaded poly(AAc/AM/SH) SAHs were not undergone any regeneration process and directly applied to adsorb phosphate ion from another waste solution. The SAHs poly(AAc-AM-SH) was anionic in nature, thus show higher affinity toward Cu2+ ions, but it hardly adsorb anions due to its characteristics of negative charge existing on the polymeric surface. The adsorption of Cu2+ makes it positively charged moiety and so it is being capable of anions/anionic dye adsorption. The various factors affecting the phosphate adsorption including pH, contact time, initial concentration of the phosphate were systematically investigated. The maximum phosphate adsorption was obtained 87.62 mg/g. The adsorption data fitted the Langmuir adsorption isotherm. The desorption studies showed that the regeneration of the poly(AAc/AM/SH)–Cu SAHs adsorbent can be easily achieved. The results confirmed that poly (AAc/AM/SH) superabsorbent hydrogels loaded with Cu2+ ion can be applied as effective solid adsorbent for the removal of phosphate ions from waste water and aqueous effluents.

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References

  • Arai Y, Sparks DL (2001) J of Colliod Interface Sci 241:317

    Article  CAS  Google Scholar 

  • Ho YS, Huang CIT, Huang HW (1999) Process Bio Chem 37:1421

    Google Scholar 

  • Huang W, Wang S, Zhu Z, li L, Yao X, Rudolph V, Haghseresht F (2008). J of Hazard Mater 158: 35

    Google Scholar 

  • Jaroniec M (1983) Physical adsorption on heterogeneous solids. Adv Colloid Interface Sci 18:149

    Article  CAS  Google Scholar 

  • Kara L, Uzun N, Denizli A (2004) Poly(ethylene glycol dimethacrylate-n-vinyl imidazole) beads for heavy metal removal. J Mater Hazard B106:93

    Article  Google Scholar 

  • Karadag E, Saraydin D, Guven O (1995) Behaviors of acrylamide itaconic acid hydrogels in uptake of uranyl ions from aqueous solutions. Sep Sci Technol 30:3287

    Article  Google Scholar 

  • Langmuir IJ (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361

    Article  CAS  Google Scholar 

  • Lee SM, Davis AP (2001) Water Res 35:534

    Google Scholar 

  • Mahadavinia GR, Pourjavadi A, Hosseinzadeh H, Zohuriaan MJ (2004) Modified chitosan 4 Superabsorbent hydrogels from acrylic acid -co-acrylamide) grafted chitosan with salt and pH-responsive prperties. Eur Polymer J 40:1399–1407

    Article  Google Scholar 

  • Mattigod SV, Fryxell GE, Parker K (2007) Inorg Chem Mun 10: 646

    Google Scholar 

  • Perrin DD, Dempsey B (1974) Chapman and Hall, London

    Google Scholar 

  • Singh T, Singhal R (2012) Poly (acrylic acid/acrylamide/sodium humate) superabsorbent hydrogels for metal ion/dye adsorption: effect of sodium humate concentration. J Appl Polym Sci 125:1267

    Article  CAS  Google Scholar 

  • Wang J, Lin W (2008) J Appl Polym Sci 109:318

    Google Scholar 

  • Wang W, Wang A (2009) Synthesis, swelling behaviors, and slow-release characteristics of a Guar Gum-g-Poly(sodium acrylate)/Sodium humate superabsorbent. J Appl Polym Sci 112:2102

    Google Scholar 

Download references

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Correspondence to Reena Singhal .

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Singh, T., Singhal, R. (2018). Efficient and Economical Application of a Spent Waste Adsorbent Cu2+-Loaded Poly (AAc-AM-SH) Superabsorbent Hydrogels by Reusing It for Adsorption of Phosphate Ion. In: Singh, V., Yadav, S., Yadava, R. (eds) Water Quality Management. Water Science and Technology Library, vol 79. Springer, Singapore. https://doi.org/10.1007/978-981-10-5795-3_22

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