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Coagulation Performance Evaluation of Natural and Synthetic Coagulants for the Treatment of Sugar Wash

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Waste Water Recycling and Management

Abstract

Distillery spent wash is the residual liquid waste generated during the production of alcohol. The pollution caused from it is one of the most critical environmental problems. The distillery spent wash poses a serious threat to the water quality in several regions in and around the environment due to its characteristics such as high organic load, dark brown color, unpleasant odor, a high temperature, low pH, and high percentage of dissolved organic and inorganic matters which may be present as reducing sugars. The removal of organic compounds along with the color from distillery effluent is a challenging criterion to the sugar industries. The characterization of various physicochemical aspects of spent wash leads to the innovation of sugar wash, the dilution of the spent wash with sugar effluent. An attempt has been made to treat this industrial effluent with coagulating agents, chemical calcium hypochlorite, and alum and natural coagulant, Moringa oleifera L. seed powder for the reduction of the pollutant. Combined chemical and natural coagulant was found to be effective in sugar wash treatment with 82% of TDS and 84% of COD removal. Thus, the present investigation states that the distillery industrial effluent spent wash could be diluted with the sugar effluent to narrow down the pollutant load to 20% and also to avoid the use of water to dilute the effluent. Alum, the most widely used chemical coagulant was reported to produce Alzheimer’s disease. Hence, M. oleifera L. seed was substituted for the treatment along with the cost-effective chemical calcium hypochlorite. The combined CaOCl2 + Moringa seed (2.75 g + 5 g) treatment produced the best pollutant removal effect.

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References

  1. Ahmad R (2005) Studies on the chemistry control of some selected drinking and industrial waters. Pak J Sci Ind Res 48(3):174–179

    Google Scholar 

  2. Qadeer R (2004) Pollution in drinking water: their sources, harmful effects and removal procedures. J Chem Soc Pak 26:293–301

    CAS  Google Scholar 

  3. Kalaiselvi P, Mahimairaja S (2009) Effect of biomethanated spent wash on soil enzymatic activities. BRI 2(4):267–272

    CAS  Google Scholar 

  4. Diangan JR, Perez MT, Claveria R (2008) Analysis of land application as a method of disposal of distillery effluent. Int J Env Health 2:258–271

    Article  CAS  Google Scholar 

  5. Pant Adholeya A (2007) Biological approaches for treatment of distillery waste water a review. Bioresour Technol 98:2321–2334

    Article  Google Scholar 

  6. Sathyawali Y, Balakrishnan M (2008) Waste water Treatment in molasses based alcohol distilleries for COD and colour removal: a review. J Environ Manage 86:481–497

    Article  Google Scholar 

  7. Coca M, Garcia Gonzalez, Penna (2004) Study of colored components formed in sugar beet processing. Food Chem 86(3):421–433

    Article  CAS  Google Scholar 

  8. Plavsic M, Cosovic B, Lee C (2006) Copper complexing properties of melanoidins and marine humic material. Sci Total Environ 366:310–319

    Article  CAS  Google Scholar 

  9. Borrelli RC, Mennella C, Barba F, Russo M, Russo GL, Krome K, Erbersdobler HF, Faist V, Fogliano V (2003) Characterization of coloured compounds obtained by enzymatic extraction of bakery products. Food Chem Toxicol 41:1367–1374

    Article  CAS  Google Scholar 

  10. Silvan JM, Lagemaat JVD, Olano A, Castillo MDD (2006) Analysis and biological properties of amino acid derivates formed by Maillard reaction in foods. J Pharma Biomed Anal 41:1543–1551

    Article  CAS  Google Scholar 

  11. Evershed RP, Bland HA, Van Bergen PF, Carter JF, Horton MC, Rowley-Conwy PA (1997) Volatile compounds in archaeological plant remains and the Maillard reaction during decay of organic matter. Science 278(5337):432–433

    Article  CAS  Google Scholar 

  12. Kumar P, Chandra R (2006) Decolourisation and detoxification of synthetic molasses melanoidins by individual and mixed cultures of Bacillus spp. Biores Technol 7:2096–2102

    Article  Google Scholar 

  13. Mohana S, Desai C, Madamwar D (2007) Biodegradation and decolourisation of anaerobically treated distillery spent wash by a novel bacterial consortium. Biores Technol 98:333–339

    Article  CAS  Google Scholar 

  14. Chandra R, Singh H (1999) Chemical decolourisation of anaerobically treated distillery effluent. Ind J Environ Prot 19(11):833–837

    CAS  Google Scholar 

  15. Kim SB, Hayase F, Kato H (1985) Decolourisation and degradation products of melanoidins on ozonolysis. Agric Biol Chem 49:785–792

    CAS  Google Scholar 

  16. Goto M, Nada T, Ogata A, Kodama A, Hirrose (1998) Supercritical water oxidation for the destruction of municipal excess sludge and alcohol distillery waste water of molasses. J Supercrit Fluid 13:277–282

    Article  CAS  Google Scholar 

  17. Jones SC, Sotriopoulus F, Amirtharajah A (2002) Numerical modelling of helical static mixer for water treatment. J Environ Eng ASCE 128:431–440

    Article  CAS  Google Scholar 

  18. Zhao W, Ting YP, Chen JP, Xing CH, Shi SQ (2000) Advanced primary treatment of wastewater using a bio flocculation adsorption sedimentation process. Acta Biotechnol 20:53–64

    Article  CAS  Google Scholar 

  19. Tripathi S, Rathore VK, Gokhale J, Agrawal P (2012) Some study on M. oleifera (drumstick) seed as natural coagulants for treatment of distillery waste water. Int J Appl Eng Technol 2(2):24–30 (ISSN: 2277-212X)

    Google Scholar 

  20. APHA (American Public Health Association) (2012) Standard methods for the examination of water and wastewater, 22nd edn. APHA, Washington

    Google Scholar 

  21. Hussian S, Mane V, Pradhan V, Faroogui M (2012) Efficiency of seeds of Moringa oleifera in estimation of water turbidity. Int J Res Pharmaceut Biomed Sci 3(3):1334–1337

    Google Scholar 

  22. Bhaskar MC, Kayalvizhi, Subash Chandra Bose M (2005) Ecofriednly utilization of distillery effluent in agriculture a review. Agri Rev 24(1):16–23

    Google Scholar 

  23. Rajukkannu K, Manickan TS (1997) Use of distillery and sugar industry waste in agriculture. In: Proceedings of 6th national symposium of environment, Tamil Nadu Agriculture University, Coimbatore, pp 286–290

    Google Scholar 

  24. Thiyagarajan TM (2001) Use of distillery effluent in agriculture: problems and perspectives. In Proceedings of national seminar on use of poor quality water and sugar industrial effluents in agriculture. ADAC and RI, Tamil Nadu Agriculture University, Tiruchirapalli, pp 1–5

    Google Scholar 

  25. Ayyasamy PM, Yasodha R, Rajakumar S, Lakshmanaperumalsamy P, Rahman PKSM, Lee S (2008) Impact of sugar factory effluent on the growth and biochemical characteristics of terrestrial and aquatic plants. Bull Environ Contam Toxicol 81:449–454

    Article  CAS  Google Scholar 

  26. Memon AR, Soomro SA, Ansari AK (2006) Sugar industry effluent-characteristics and chemical analysis. J App Env Sci 1:152–157

    Google Scholar 

  27. Thamaraiselvi C, Sowmiya Rajalakshmi B, Ahila KG, Ancy Jenifer A (2014) Bioremidiation of sugar wash using natural scavengers. Int J Res Dev Pharm Life Sci 3(6):1310–1315

    CAS  Google Scholar 

  28. Ancy Jenifer A, Thamaraiselvi C (2014) Eco-friendly treatment of coir ret waste water using natural coagulant. Int J Inf Futuristic Res 2(4):882–893

    Google Scholar 

  29. Edward JK (1993) Coagulation in drinking water treatment particles. Organics and coagulants. Water Sci Technol 27:21–35

    Article  Google Scholar 

  30. Teresa ZP, Guntha G, Fernando H (2007) Chemical oxygen demand reduction in coffee wastewater through chemical flocculation and advanced oxidation processor. J Environ Sci 300–305

    Google Scholar 

  31. Drosatle RL (1997) Theory and practice of water and waste water treatment. Wiley, Hoboken, Canada

    Google Scholar 

  32. Novita E, Sudajanlo G, Bayartyo AY (2012) Chemical coagulation of coffee waste water for smallholder coffee agro industry engineering goes green, 7th cuks conference, pp 6–7

    Google Scholar 

  33. Hanif IMA, Riaz MS, Noureen S, Ansari TM, Bhatti HN (2012) Coagulation/flocculation of tannery waste water using immunobilized chemical coagulants. J Appl Res Technol 10(2):79–86

    Google Scholar 

  34. Brostlap AC, Schuurmans J (1988) Kinetics of Valine uptake in tobacco leaf disc. Comparison of wild types the digenic mutant and its monogenic derivatives. Planta 176:42–50

    Article  Google Scholar 

  35. Costa G, Michant JC, Guckert G (1997) Amino acids exuded form cadmium concentrations. J Plant Nutr 20(7–8):883–900

    Article  CAS  Google Scholar 

  36. Delvin S (2002) Amino acids and proteins, 1st edn. IVY Publishing House, New-Delhi, p 53

    Google Scholar 

  37. Padmapriya R, Tharian JA, Thirunalasundari T (2015) Treatment of coffee effluent by Moringa oleifera seed. Int J Curr Microbiol Appl Sci

    Google Scholar 

  38. Jahn SA (1986) Proper use of African natural coagulants for rural water supplies: research in the Sudan and a guide for new projects. Deutsche Gesellschaft fur Technische Zusammenarbeit (GTZ) GmbH, Eschborn

    Google Scholar 

  39. Gidde MR, Bhalerao A, Majithiya HM (2008) Moringa oleifera-household alternative coagulant for water treatment. In: Paper for national conference household water treatment technology at college of science and technology, Mathura, pp 1–8

    Google Scholar 

  40. Thirupathaiah M, Samatha C, Sammaiah C (2012) Analysis of water quality using physico-chemical parameters in lower Manair reservoir of Karimnagar district, Andhra Pradesh. Int J Environ Sci 3(1):172–180

    CAS  Google Scholar 

  41. Bahar M, Reza MS (2010) Hydrochemical characteristics and quality assessment of shallow groundwater in a coastal area of Southwest Bangladesh. Environ Earth Sci 61:1065–1073

    Article  CAS  Google Scholar 

  42. Edet A, Nganje TN, Ukpong AJ, Ekwere AS (2011) Groundwater chemistry and quality of Nigeria: a status review. Afr J Environ Sci Technol 5(13):1152–1169

    CAS  Google Scholar 

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Acknowledgements

The authors kindly acknowledge DST-SERB for providing financial assistance to carry out the investigation successfully.

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Correspondence to Muthunarayanan Vasanthy .

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Thamaraiselvi, C., Ancy Jenifer, A., Vasanthy, M. (2019). Coagulation Performance Evaluation of Natural and Synthetic Coagulants for the Treatment of Sugar Wash. In: Ghosh, S. (eds) Waste Water Recycling and Management. Springer, Singapore. https://doi.org/10.1007/978-981-13-2619-6_5

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