Abstract
Magnetic particle is one of the main elements used in magnetorheological (MR) materials. In this study, the magnetic cobalt ferrite nanoparticles are successfully synthesized via co-precipitation method at different sintering temperatures. The nanoparticles are prepared in neutral condition (pH 7) at different temperatures of 900, 1000 °C for 8 h, individually. The properties of cobalt ferrite related to phase analysis, microstructure and magnetic properties were characterized by particle size analyzer (PSA), field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). The result showed that the size of cobalt ferrite powders are 16.72, 17.76 and 37.29 nm correspond to different temperatures of 900, 1000 and 1100 °C, respectively. This indicated that the higher sintering temperature induced to the synthesized cobalt ferrite, greater size of the nanoparticles will be obtained. Meanwhile, the micrograph of cobalt ferrite powders poses a polygonal shape with all exhibit the face centered cubic (FCC) structure. In the meantime, the magnetic saturation, Ms increased with the size of nanoparticles increased from 28.95 to 38.85 emu/g, simultaneously correspond to increasing in the sintering temperatures. The results underlined that the sintering temperature did affect and alter the size of CoFe2O4 nanoparticles that resulted in magnetic properties enhancement.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Rahman NANA, Mazlan SA, Aziz SAA., Nordin NA, Ubaidillah R, Hapipi N (2018) Magnetorheological elastomer silicone-based containing corroded carbonyl iron particles. Key Eng Mater 772:51–55
Ubaidillah R, Sutrisno J, Purwanto A, Mazlan SA (2015) Recent progress on magnetorheological solids: materials, fabrication, testing, and applications. Adv Eng Mater 17(5):563–597
Wahid SA, Ismail I, Aid S, Rahim MSA (2014) Magneto-rheological defects and failures: a review. IOP Conf Ser: Mater Sci Eng 114
Kurian M, Thankachan S, Nair DS, Aswathy EK, Babu A, Thomas A, Binu Krishna KT (2015) Structural, magnetic, and acidic properties of cobalt ferrite nanoparticles synthesised by wet chemical methods. J Adv Ceram 4(3):199–205
Sagadevan S, Podder J, Das I (2017) Synthesis and characterization of cobalt ferrite (CoFe2O4) nanoparticles prepared by hydrothermal method. In: Recent trends in materials science and applications, pp 145–152
Stein CR, Bezerra MTS, Holanda GHA, André-Filho J, Morais PC (2018) Structural and magnetic properties of cobalt ferrite nanoparticles synthesized by co-precipitation at increasing temperatures. AIP Adv 8(5)
Ristic M, Krehula S, Reissner M, Jean M, Hannoyer B, Musić S (2017) Synthesis and properties of precipitated cobalt ferrite nanoparticles. J Mol Struct 1140:32–38
Olusegun SJ, Freitas ETF, Lara LRS, Stumpf HO, Mohallem NDS (2019) Effect of drying process and calcination on the structural and magnetic properties of cobalt ferrite. Ceram Int 45(7):8734–8743
Liu C, Rondinone AJ, Zhang ZJ (2000) Synthesis of magnetic spinel ferrite CoFe2O4 nanoparticles from ferric salt and characterization of the size-dependent superparamagnetic properties. Pure Appl Chem 72(1–2):37–45
Hunyek A, Sirisathitkul C, Harding P, Harding DJ (2012) Structural and magnetic properties of cobalt ferrites synthesized using sol-gel techniques. Mater Sci-Poland 30(3):278–281
Shinde AB (2013) Structural and electrical properties of cobalt ferrite nanoparticles. Int J Innov Technol Explor Eng 3(4)
Swatsitang E, Phokha S, Hunpratub S, Usher B, Bootchanont A, Maensiri S, Chindaprasirt P (2016) Characterization and magnetic properties of cobalt ferrite nanoparticles. J Alloy Compd 664:792–797
Xavier S, Thankachan S, Jacob BP, Mohamed EM (2013) Effect of sintering temperature on the structural and magnetic properties of cobalt ferrite nanoparticles. Nanosyst: Phys Chem Math 4(3):430–437
Syamimi NF, Amin Matori K, Lim WF, Abdul Aziz S, Mohd Zaid MH (2014) Effect of sintering temperature on structural and morphological properties of europium (III) oxide doped willemite. J Spectrosc 1–8
Kumar L, Kar M (2011) Effect of annealing temperature and preparation condition on magnetic anisotropy in nanocrystalline cobalt ferrite. IEEE Trans Magn 47(10):3645–3648
Bjørk R, Tikare V, Frandsen HL, Pryds N, Blendell J (2013) The effect of particle size distributions on the microstructural evolution during sintering. J Am Ceram Soc 96(1):103–110
Issa B, Obaidat IM, Albiss BA, Haik Y (2013) Magnetic nanoparticles: surface effects and properties related to biomedicine applications. Int J Mol Sci 14(11):21266–21305
Acknowledgements
This study was financially supported by the Universiti Teknologi Malaysia under Trans-disciplinary Research Grant (Vot No: 07G13) and Fundamental Research Grant Scheme (Vot No: 5F001). The authors acknowledge and thank MJIIT Microscopy Laboratory for assistance for this study.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Tarmizi, S.M.A. et al. (2020). Effect of High Sintering Temperature on the Cobalt Ferrite Synthesized Via Co-precipitation Method. In: Sabino, U., Imaduddin, F., Prabowo, A. (eds) Proceedings of the 6th International Conference and Exhibition on Sustainable Energy and Advanced Materials. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-15-4481-1_23
Download citation
DOI: https://doi.org/10.1007/978-981-15-4481-1_23
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-15-4480-4
Online ISBN: 978-981-15-4481-1
eBook Packages: EngineeringEngineering (R0)