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Transition metal complexes of (strained) cyclophanes

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Cyclophanes

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 172))

Abstract

Numerous transition metal complexes of strained cyclophanes are known, including the metals Cr, Mo, W, Fe, Ru, Co, Rh, Ir, Ni, Cu, Ag and U. The complexed phanes turned out to be valuable subjects for NMR-examinations in order to draw a map of the magnetic environment of sandwich complexes, e.g. di(benzene)chromium and ferrocene, and they provided an insight into the effect of ring current disrupture, due to metal complexation. First attempts were carried out to derivatize the cyclophanes using the metal fragment as an auxiliary group, which is easily introduced as well as removed. In this context a tricarbonylchromium complex of a chiral [2.2]metacyclophane was prepared recently and its absolute configuration, containing two elements of chirality, was determined by X-ray crystallography. Complexation of the cyclophanes was also used for the purpose of the preparation of numerous novel phanes which were not yet available via other routes, e.g. syn-[2.2]metacyclophane, and phanes, which contain anti-aromatic π-decks and are only stable when complexed with the metal. Removing the stabilizing metal unit lead to valence isomerism, which gave interesting hydrocarbons, e.g. propella[34]prismane.

The synthesis of [4]ferrocenophane, containing an iron-II-ion in the center of the hydrocarbon cage, has been achieved recently. The closely related [3]- and

Of increasing interest is the construction of an organometallic polymer, containing alternating phane and metal units, because of its use as an electrical conductor. The first oligomeric units of such a polymer have already been prepared, using either iron-II, coordinated to indenophanes, or ruthenium-II, coordinated sandwich-like to multibridged [2n]cyclophanes. The 2-electron reduction product of the sandwich complex of the bis(ruthenium-II) complex with [24](1,2,4,5)cyclophane, the most stable in this series, establishes the first example, where a netto-2-electron intervalence transfer of a discrete, mixed-valence organometallic complex was observed.

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Schulz, J., Vögtle, F. (1994). Transition metal complexes of (strained) cyclophanes. In: Weber, E. (eds) Cyclophanes. Topics in Current Chemistry, vol 172. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0025267

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