CAS Registry Number: 56293-29-9
Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinolizidine Alkaloids
Biological sources: Leptorhabdos parviflora, Sophora alopecuroides
C15H24N2: 232.194
Mp: 72°C (petr. ether), 265°C (dihydrochloride), 208°C (hydrochloride) [1]
[α]D +82° (c 0.854, EtOH)
MS m/z: 232(M+), 203, 189, 174, 148, 134, 98, 97, 96, 84, 83 [1]
1 H NMR: 1.79(1H, H-7), 2.26(1H, 2J15 = 13.5, J15,13e = 2.2, J15,14e = 2.2, He-15), 2.45(1H, q, J = 3.4, 12, Ha-10), 2.66(1H, J13,14a = 9, 2J13 = 12, Ha-13), 2.86(1H, q, J = 5.2, 12, He-10), 3.08(1H, 2J13 = 12, He-13), 3.11(1H, d, J = 6.3, H-11), 5.40(1H, d, J7,17 = 6.5, H-17) [1]
X-ray: [2]
Abs. Conf.: 6R7R9R11S [2]
HPLC, GC: [3]
Pharm./Biol.: Stimulating action. Raises arterial pressure and stimulates respiration [4]
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References
O.N. Tolkachev, T.E. Monakhova, V.I. Sheichenko, V.S. Kabanov, O.G. Fesenko, N.F. Proskurnina, Chem. Nat. Comp. 11, 29 (1975)
A.D. Brosius, J.W. Ziller, Q. Zhang, Acta Cryst. C. 53, 1510 (1997)
X. Chen, C.Q. Yi, X.Q. Yang, X. Wang, J. Chromatogr. B 812, 149 (2004)
T.E. Monakhova, Author’s Abstract of Candidate’s Dissertation, Moscow, 1975
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(2013). Aloperine. In: Azimova, S.S., Yunusov, M.S. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0560-3_1206
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