Zusammenfassung
Aufgrund seiner Robustheit wird der Rührkesselreaktor industriell am meisten genutzt. Für bestimmte Anwendungen, insbesondere in der Hochdrucktechnik oder bei stark exothermen Reaktionen, sind Rohrreaktoren eine sehr gute Alternative. Im Vergleich zu geraden Rohrreaktoren ist in Wendelrohrreaktoren der radiale Wärme- und Stoffaustausch deutlich intensiviert, ohne dass aktiv zusätzlich Energie zugeführt werden muss. Im vorliegenden Kapitel werden die Eigenschaften der Wendelrohrreaktoren näher erläutert und konventionellen Rohrreaktoren gegenübergestellt.
This is a preview of subscription content, log in via an institution to check access.
Literatur
Abdel-Aziz, M.H., Mansour, I.A.S., Sedahmed, G.H.: Study of the rate of liquid solid mass transfer controlled processes in helical tubes under turbulent flow conditions. Chem. Eng. Process. 49, 643–648 (2010). https://doi.org/10.1016/j.cep.2009.06.004
Aris, R.: On the dispersion of a solute in a fluid flowing through a tube. Proc. R. Soc. Lond. A Math. Phys. Sci. 235, 67–77 (1956). https://doi.org/10.1098/rspa.1956.0065
Awwad, A., Xin, R., Dong, Z., Ebadian, M., Soliman, H.: Flow patterns and pressure drop in air/water two-phase flow in horizontal helicoidal pipes. J. Fluids Eng. 117(4), 720–726 (1995). https://doi.org/10.1115/1.2817328
Baerns, M., Behr, A., Brehm, A., Gmehling, J., Hofmann, H., Onken, U., Renken, A.: Technische Chemie, Bd. 1. WILEY-VCH Verlag GmbH & Co.KGaA, Weinheim (2006)
Banerjee, S., Rhodes, E., Scott, D.S.: Film inversion of focurrent two-phase flow in helical coils. AIChE J. 13(1), 189–191 (1967). https://doi.org/10.1002/aic.690130137
Banerjee, S., Rhodes, E., Scott, D.S.: Studies on cocurrent gas-liquid flow in helically coiled tubes: I. Flow patterns, pressure drop and holdup. Can. J. Chem. Eng. 47, 445–453 (1969). https://doi.org/10.1002/cjce.5450470509
Banerjee, S., Scott, D.S., Rhodes, E.: Studies on cocurrent gas liquid flow in helically coiled tubes II. Theory and experiments on turbulent mass transfer with and without chemical reaction. Can. J. Chem. Eng. 48, 542–551 (1970). https://doi.org/10.1002/cjce.5450470509
Castelain, C., Mokrani, A., Legentilhomme, P., Peerhossaini, H.: Residence time distribution in twisted pipe flows: helically coiled system and chaotic system. Exp Fluids 22, 359–368 (1997). https://doi.org/10.1007/s003480050061
Charpentier, J.-C.: Mass-transfer rates in gas-liquid absorbers and reactors. Adv. Chem. Eng. 11, 1–133 (1981). https://doi.org/10.1016/S0065-2377(08)60025-3
Czop, V., Barbier, D., Dong, S.: Pressure drop, void fraction and shear stress measurements in an adiabatic two-phase flow in a coiled tube. Nucl. Eng. Des. 149(1–3), 323–333 (1994). https://doi.org/10.1016/0029-5493(94)90298-4
Dreimann, J., Lutze, P., Zagajewski, M., Behr, A., Górak, A., Vorholt, A.J.: Highly integrated reactor–separator systems for the recycling of homogeneous catalysts. Chem. Eng. Process. 99, 124–131 (2016). https://doi.org/10.1016/j.cep.2015.07.019
Erdogan, M.E., Chatwin, P.C.: The effects of curvature and buoyancy on the laminar dispersion of solute in a horizontal tube. J. Fluid Mech. 29(3), 465–484 (1967). https://doi.org/10.1017/S0022112067000977
Fsadni, A.M., Whitty, J.P.M.: A review on the two-phase pressure drop characteristics in helically coiled tubes. Appl. Therm. Eng. 103, 616–638 (2016). https://doi.org/10.1016/j.applthermaleng.2016.04.125
Garimella, S., Richards, D.E., Christensen, R.N.: Experimental investigation of heat transfer in coiled annular ducts. J. Heat Transf. 110(2), 329–336 (1988)
Guo, L., Feng, Z., Chen, X.: An experimental investigation of the firctional prssure drop of steam-water two-phase flow in helical coils. Int. J. Heat Mass Transf. 44, 2601–6210 (2001). https://doi.org/10.1016/S0017-9310(00)00312-4
Herrmann, C., Hübinger, W., Kremeskötter, J., Minges, R., Schmidt-Thümes, J., Moritz, H.U., Schmidt, W., Ridder, M.: Vorrichtung zur kontinuierlichen Durchführung chemischer Reaktionen. Deutschland WO 98/08602 Patent ( 1998)
Hewitt, G.F., Jayanti, A.: Prediction of film inversion in two-phase flow in coiled tubes. J. Fluid Mech. 236, 497–511 (1992). https://doi.org/10.1017/S0022112092001502
Jespen, J.C.: Mass transfer in two-phase flow in horizontal pipelines. AIChE J. 16(5), 705–711 (1970). https://doi.org/10.1002/aic.690160504
Johnson, M.D., May, S.A., Calvin, J.R., Remacle, J., Stout, J.R., Diseroad, W.D., Zaborenko, N., Haeberle, B.D., Sun, W.-M., Miller, M.T., Brennan, J.: Development and scale-up of a continuous, high-pressure, asymmetric hydrogenation reaction, workup, and isolation. Org. Res. Dev. 16, 1017–1038 (2012). https://doi.org/10.1021/op200362h
Johnson, M.J., May, S.A., Haeberle, B., Lambertus, G.R., Pulley, S.R., Stout, J.R.: Design and comparison of tubular and pipes-in-series continuous reactors for direct asymmetric reductive amination. Org. Process Res. Dev. 20, 1305–1320 (2016). https://doi.org/10.1021/acs.oprd.6b00137
Jokiel, M., Wagner, L.-M., Mansour, M., Kaiser, N.M., Zähringer, K., Janiga, G., Nigam, K.D.P., Thévenin, D., Sundmacher, K.: Measurement and simulation of mass transfer and backmixing behavior in a gas-liquid helically coiled tubular reactor. Chem. Eng. Sci. 170, 410–421 (2017). https://doi.org/10.1016/j.ces.2017.01.027
Jokiel, M., Kaiser, N.M., Kovats, P., Mansour, M., Zähringer, K., Nigam, K.D.P., Sundmacher, K.: Helically coiled segmented flow tubular reactor for the hydroformylation of long-chain olefins in a thermomorphic multicomponent solvent system. Chem. Eng. J. (2018). https://doi.org/10.1016/j.cej.2018.09.221
Kaiser, N.M., Jokiel, M., McBride, K., Flassig, R.J., Sundmacher, K.: Optimal reactor design via flux profile analysis for an integrated hydroformylation process. Ind. Eng. Chem. Res. 56, 11507–11518 (2017). https://doi.org/10.1021/acs.iecr.7b01939
Kasturi, G., Stepanek, J.B.: Two phase flow I. Pressure drop and void fraction measurements in concurrent gas-liquid flow in a coil. Chem. Eng. Sci. 27, 1871–1880 (1972). https://doi.org/10.1016/0009-2509(72)85049-8
Koutsky, J.A., Adler, R.J.: Minimization of axial dispersion by use of secondary flow in helical tubes. Can. J. Chem. Eng. 42, 239–246 (1964). https://doi.org/10.1002/cjce.5450420602
Kováts, P., Pohl, D., Thévenin, D., Zähringer, K.: Optical determination of oxygen mass transfer in a helically-coiled pipe compared to a straight horizontal tube. Chem. Eng. Sci. 190, 273–285 (2018). https://doi.org/10.1016/j.ces.2018.06.029
Kulic, E., Rhodes, E.: Chemical mass transfer in co current gas-liquid slug flow in helical coils. Can. J. Chem. Eng. 52, 114–116 (1974). https://doi.org/10.1002/cjce.5450520118
Kumar, V., Aggarwal, M., Nigam, K.D.P.: Mixing in curved tubes. Chem. Eng. Sci. 61, 5742–5753 (2006). https://doi.org/10.1016/j.ces.2006.04.040
Kumar, V., Mridha, M., Gupta, A.K., Nigam, K.D.P.: Coiled flow inverter as heat exchanger. Chem. Eng. Sci. 62, 2386–2396 (2007). https://doi.org/10.1016/j.ces.2007.01.032
Kumar, T.A., Raju, G.M.J., Sarma, G.V.S., Ramesh, K.V.: Mass transfer at the confining wall of helically coiled circular tubes with gas-liquid flow and fluidized bed. Chem. Eng. J. 153, 114–119 (2009). https://doi.org/10.1016/j.cej.2009.02.039
Kumar, R.H., Ramesh, K.V., Sarma, G.V.S., Raju, G.M.J.: Mass transfer at the confining wall of helically coiled circular tubes in the absence and presence of packed solids. Int. Commun. Heat Mass Transfer 38, 319–323 (2011). https://doi.org/10.1016/j.icheatmasstransfer.2010.11.008
Kurt, S.K., Gürsel, I.V., Hessel, V., Nigam, K.D.P., Kockmann, N.: Liquid–liquid extraction system with microstructured coiled flow inverter and other capillary setups for single-stage extraction applications. Chem. Eng. J. 284, 764–777 (2016). https://doi.org/10.1016/j.cej.2015.08.099
Kurt, S.K., Warnebolda, F., Nigam, K.D.P., Kockmann, N.: Gas-liquid reaction and mass transfer in microstructured coiled flow inverter. Chem. Eng. Sci. 169, 164–178 (2017). https://doi.org/10.1016/j.ces.2017.01.017
Levenspiel, O.: Chemical Reaction Engineering, 3. Aufl. Wiley, New York/Chiochester/Weinheim/Brisbane/Singapore/Toronto (2004)
Levenspiel, O.: The chemical reactor omnibook. Print on Demand by Lulu.com (2013)
Lobedann, M., Klutz, S., Kurt, S.K.: Device and method for continuous virus inactivation. US 2016/0375159 A1 Patent (2016)
Lockhart, R.W., Martinelli, R.C.: Proposed correlation of data for isothermal two-phase, two-component flow in pipes. Chem. Eng. Prog. 45, 39–48 (1949)
López-Guajardo, E., Ortiz-Nadal, E., Montesinos-Castellanos, A., Nigam, K.D.P.: Coiled flow inverter as a novel alternative for the intensification of a liquid-liquid reaction. Chem. Eng. Sci. 169, 179–185 (2017). https://doi.org/10.1016/j.ces.2017.01.016
Mandal, S.M., Das, S.K.: Gas-liquid flow through helical coils in horizontal orientation. Can. J. Chem. Eng. 80, 979–983 (2002). https://doi.org/10.1002/cjce.5450800522
Mansour, M., Liu, Z., Janiga, G., Nigam, K.D.P., Sundmacher, K., Thévenin, D., Zähringer, K.: Numerical study of liquid liquid mixing in helical pies. Chem. Eng. Sci. 172, 250–261 (2017). https://doi.org/10.1016/j.ces.2017.06.015
Mazubert, A., Crockatt, M., Poux, M., Aubin, J., Roelands, M.: Reactor comparison for the esterification of fatty acids from waste cooking oil. Chem. Eng. Technol. 12(38), 2161–2169 (2015). https://doi.org/10.1002/ceat.201500138
Mishra, P., Gupta, S.N.: Momentum transfer in curved pipes. 1. Newtonian fluids. Ind. Eng. Chem. Process. Des. Dev. 18(1), 131–137 (1979). https://doi.org/10.1021/i260069a017
Mridha, M., Nigam, K.D.P.: Coiled flow inverter as an inline mixer. Chem. Eng. Sci. 63, 1724–1732 (2008). https://doi.org/10.1016/j.ces.2007.10.028
Müller, M., Cunningham, M.F., Hutchinson, R.A.: Continious atom transfer radical polymerization in a tubular reactor. Mol. React. Eng. 2, 31–36 (2008). https://doi.org/10.1002/mren.200700029
Nauman, E.B.: The residence time distribution for laminar flow in helically coiled tubes. Chem. Eng. Sci. 32, 287–293 (1977). https://doi.org/10.1016/0009-2509(77)80207-8
Nauman, E.B.: Chemical Reactor Design, Optimization, and Scaleup, 2. Aufl. Wiley, Hoboken (2008)
Nigam, K.D.P., Saxena, A.K.: Residence time distribution in straight and curved tubes. In: Chermisinoff, N.P. (Hrsg.) Encyclopedia of Fluid Mechanics, Bd. 1, S. 675–762. Gulf Publishing Co., Morganville (1986)
Nunge, R.J., Lin, T.-S., Gill, W.N.: Laminar dispersion in curved tubes and channels. J. Fluid Mech. 51(2), 363–383 (1972). https://doi.org/10.1017/S0022112072001247
Runstraat, A.V.D., Geerdink, P., Lawrence, E., Goether, V.: Process and appratus for carrying out multi-phase reactions. Nederlande Patent, US2011/0112216 A1 (2011)
Ruthven, D.M.: The residence time distribution for ideal laminar flow in a helical tube. Chem. Eng. Sci. 26(I), 113–112 (1971). https://doi.org/10.1016/0009-2509(71)80025-8
Sauer, J., Dahem, N., Henrich, E.: Tubular plug flow reactors. In: Ullmann’s Encyclopedia of Industrial Chemistry, Electronic Release. Wiley-VCH, Weinheim (2013)
Saxena, A.K., Nigam, K.D.P.: Effect of coil pitch and cross-sectional ellipticity on RTD for diffusion-free laminar flow in coiled tubes. Chem. Eng. Commun. 23(4–6), 277–289 (1983a). https://doi.org/10.1080/00986448308940479
Saxena, A.K., Nigam, K.D.P.: Laminar dispersion in helically coiled tubes of square cross-section. Can. J. Chem. Eng. 61, 53–57 (1983b). https://doi.org/10.1002/cjce.5450610109
Saxena, A.K., Nigam, K.D.P.: Coiled configuration for flow inversion and its effect on residence time distribution. AIChE J. 30(3), 363–368 (1984). https://doi.org/10.1002/aic.690300303
Saxena, A.K., Nigam, K.D.P., Schumpe, A., Deckwer, W.D.: Liquid phase residence zime distribution for two phase flow in coiled tubes. Can. J. Chem. Eng. 74, 861–866 (1996). https://doi.org/10.1002/cjce.5450740607
Schmidt, E.F.: Wärmeübergang und Druckverlust in Rohrschlangen. Chem. Ing. Tech. 39(13), 781–789 (1967). https://doi.org/10.1002/cite.330391302
Shah, A.K., Sharma, M.M.: Mass transfer in a liquid liquid coil contactor. Can. J. Chem. Eng. 51, 772–775 (1973). https://doi.org/10.1002/cjce.5450510625
Sharma, L.: Persönliche Kommunikation, Indian Institute of Technology Delhi, New Delhi 110016, India. (2018)
Sharma, L., Nigam, K.D.P., Roy, S.: Axial dispersion in single and multiphase flows in coiled geometries: Radioactive particle tracking experiments. Chem. Eng. Sci. 157, 116–126 (2017a). https://doi.org/10.1016/j.ces.2016.05.012
Sharma, L., Nigam, K.D.P., Roy, S.: Single phase mixing in coiled tubes and coiled flow inverters in different flow regimes. Chem. Eng. Sci. 160, 227–235 (2017b). https://doi.org/10.1016/j.ces.2016.11.034
Singh, J., Nigam, K.D.P.: Pilot plant study for effective heat transfer area of coiled flow inverter. Chem. Eng. Process. 102, 219–228 (2016). https://doi.org/10.1016/j.cep.2016.02.001
Sreenivasan, K.R., Strykowski, P.J.: Stabilization effects of flow through helically coiled pipes. Exp. Fluids. 1, 31–36 (1983). https://doi.org/10.1007/BF00282264
Taylor, G.: Dispersion of soluble matter in solvent flowing slowly through a tube. Proc. R. Soc. Lond. Ser. A Math. Phys. 219(1137), 186–203 (1953). https://doi.org/10.1098/rspa.1953.0139
Thandlam, A.K., Das, C., Majumder, S.K.: Flow pattern-based mass and heat transfer and frictional drag of gas-non-Newtonian liquid flow in helical coil: two- and three-phase systems. Heat Mass Transf. 53, 1183–1197 (2017). https://doi.org/10.1007/s00231-016-1898-y
Trivedi, R.N., Vasudeva, K.: RTD for diffusion free laminar flow in helical coils. Chem. Eng. Sci. 29, 2291–2295 (1974). https://doi.org/10.1016/0009-2509(74)80005-9
Trivedi, R.N., Vasudeva, K.: Axial dispersion in laminar flow in helical coils. Chem. Eng. Sci. 30, 317–325 (1975). https://doi.org/10.1016/0009-2509(75)80081-9
Vashisth, S., Kumar, V., Nigam, K.D.P.: A review on the potential applications of curved geometries in process industry. Ind. Eng. Chem. Res. 47, 3291–3337 (2008). https://doi.org/10.1021/ie701760h
VDI-Gesellschaft: VDI-Wärmeatlas, Bd. 11. Springer, Berlin/Heidelberg (2013)
Verdoes, D., Goetheer, E.L.V., Hornstra-Xu, Z., Walpot, J.I.: Process and apparatus for carrying out crystallization. WO 2006/025741 A2 Patent, 2006
Wiedmeyer, V., Anker, F., Bartsch, C., Voigt, A., John, V., Sundmacher, K.: Continuous crystallization in a helically coiled flow tube: analysis of flow field, residence time behavior, and crystal growth. Ind. Eng. Chem. Res. 56, 3699–3712 (2017a). https://doi.org/10.1021/acs.iecr.6b04279
Wiedmeyer, V., Voigt, A., Sundmacher, K.: Crystal population growth in a continuous helically coiled flow tube crystallizer. Chem. Eng. Technol. 40(9), 1584–1590 (2017b). https://doi.org/10.1002/ceat.201600530
Wu, K.-J., Michtet, G., Bohan, D.V., Murciano, L.T.: Synthesis of narrow sized silver nanoparticles in the absence of capping ligands in helical microreactors. React. Chem. Eng. 2, 116–128 (2017). https://doi.org/10.1039/C6RE00202A
Xin, R.C., Ebadian, M.A.: The effects of prandtl numbers on local and average convective heat transfer characteristics in helical pipes. J. Heat Transf. 119(3), 467–473 (1997). https://doi.org/10.1115/1.2824120
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer-Verlag GmbH Deutschland, ein Teil von Springer Nature
About this entry
Cite this entry
Jokiel, M., Sundmacher, K. (2018). Spezielle labortechnische Reaktoren: Wendelrohrreaktor. In: Reschetilowski, W. (eds) Handbuch Chemische Reaktoren. Springer Reference Naturwissenschaften . Springer Spektrum, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-56444-8_46-1
Download citation
DOI: https://doi.org/10.1007/978-3-662-56444-8_46-1
Received:
Accepted:
Published:
Publisher Name: Springer Spektrum, Berlin, Heidelberg
Print ISBN: 978-3-662-56444-8
Online ISBN: 978-3-662-56444-8
eBook Packages: Springer Referenz Naturwissenschaften